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Reducible Representation for Linear Molecules

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Ian J. McNaught

School of Human and Biomedical Sciences, University of Canberra, Canberra, ACT 2601 Australia

J. Chem. Educ., 1997, 74 (7), p 809

DOI: 10.1021/ed074p809

Publication Date (Web): July 1, 1997

Abstract

Simple methods are described that permit the ready writing of reducible representations for systems described by the point groups D_infiniteh and C_infinitev. Examples of applying the methods are given to problems in vibrational and electronic spectroscopy as well as bonding theory.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Physical Chemistry

Keywords (Subject):

Theoretical Chemistry

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

A Simple Reduction Process for the Normal Vibrational Modes Occurring in Linear Molecules
William McInerny
Journal of Chemical Education2005 82 (1), 140
- A Simple Reduction Process for the Normal Vibrational Modes Occurring in Linear Molecules
  William McInerny
  Journal of Chemical Education2005 82 (1), 140
  The students in molecular spectroscopy courses are often required to determine the permitted normal vibrations for linear molecules that belong to the groups C∞ν and D∞h. The reducible group representations generated by the use of Cartesian coordinates ...
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