Article
Atomic Emission Spectra Using a UV-Vis Spectrophotometer and an Optical Fiber Guided Light Source
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Abstract
The use of an optical fiber guided light source in conjunction with a UV-Vis spectrophotometer to study the emission spectra of atomic hydrogen, sodium and helium in the undergraduate physical chemistry laboratory is described. The observed spectra have sufficient detail to allow an accurate calculation of the Rydberg constants and ionization energies of these elements. The obtained results also provide an opportunity to discuss energy level diagrams, selection rules for transitions, spin-orbit coupling magnitudes, and relative intensities of doublet lines.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Physical ChemistryKeywords (Pedagogy):
Hands-On Learning / ManipulativesKeywords (Subject):
HydrogenCiting Articles
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This article has been cited by 3 ACS Journal articles (3 most recent appear below).

UV–Visible Spectrometers: Versatile Instruments across the Chemistry Curriculum
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A Guided-Inquiry Lab for the Analysis of the Balmer Series of the Hydrogen Atomic Spectrum
A. M. R. P. BopegederaJournal of Chemical Education2011 88 (1), 77-81A Guided-Inquiry Lab for the Analysis of the Balmer Series of the Hydrogen Atomic Spectrum
A. M. R. P. BopegederaJournal of Chemical Education2011 88 (1), 77-81A guided-inquiry lab was developed to analyze the Balmer series of the hydrogen atomic spectrum. The emission spectrum of hydrogen was recorded with a homemade benchtop spectrophotometer. By drawing graphs and a trial-and-error approach, students discover ...

Emission Spectroscopy in the Undergraduate Laboratory
Scott R. Goode and Lori A. MetzJournal of Chemical Education2003 80 (12), 1455Emission Spectroscopy in the Undergraduate Laboratory
Scott R. Goode and Lori A. MetzJournal of Chemical Education2003 80 (12), 1455Simple lab experiments using an inexpensive, solid-state computerized spectrometer can help to introduce students to analytical emission spectroscopy. A series of experiments that employ an Ocean Optics spectrometer, a Windows PC, and a fiber optic pickup ...
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History
- Received: August 03, 2009
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