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Article

Stepwise Equilibria in Gas-Phase Reactions: The Alkylation of Benzene

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Eugen E. Weltin

University of Vermont, Department of Chemistry, Cook Physical Science Building, Burlington, VT 05405-0125

J. Chem. Educ., 1998, 75 (3), p 370

DOI: 10.1021/ed075p370

Publication Date (Web): March 1, 1998

Section:

History, Education, and Documentation

Abstract

The method to calculate the equilibrium composition of a stepwise attachment of a ligand to a central species is extended to equilibria in a stepwise gas-phase reactions and applied to the alkylation of benzene. For given initial amounts and given total pressure the equilibrium composition for four groups of isomers are evaluated.