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Ernest Rutherford, Avogadro's Number, and Chemical Kinetics
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Abstract
The paper presents a way for students to use data from Rutherford's works (1908 - 1911) in order to determine one of the most precise values of Avogadro Constant available at the beginning of the century. A brief discussion of earlier and modern methods for the determination of this fundamental constant is followed by vast quotations from the works of Rutherford, Boltwood and Geiger. Then there are given a dozen of problems and questions for students about these classical experiments; they vary in complexity from rather simple to quite challenging. Additional information and hints are provided to help the students in solving the problems. The last part contains detailed answers and solutions to all problems. The article will be useful for students of general chemistry, radiochemistry and physical chemistry (kinetics).
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High School / Introductory ChemistryKeywords (Domain):
Physical ChemistryKeywords (Subject):
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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Sublimination of Iodine at Various Pressures: Mutlipurpose Experiments in Inorganic and Physical Chemistry
Ilya A. LeensonJournal of Chemical Education2005 82 (2), 241Sublimination of Iodine at Various Pressures: Mutlipurpose Experiments in Inorganic and Physical Chemistry
Ilya A. LeensonJournal of Chemical Education2005 82 (2), 241The aim of this article is to elucidate some interesting phenomena, which can be observed in the process of heating solid iodine in closed vessels at various pressures. The experiments provide useful possibilities for discussing the following items: ...
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History
- Received: August 03, 2009
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