Complexation Calculations Are Worse Than Useless

Stephen J. Hawkes
Department of Chemistry, Oregon State University, Corvallis, OR 97331-4003
J. Chem. Educ., 1999, 76 (8), p 1099
DOI: 10.1021/ed076p1099
Publication Date (Web): August 1, 1999

Abstract

Calculations of complexation equilibria in introductory texts are unreliable to the point of absurdity. No case has been made that they should be taught, but if they are they should be taught using software that solves all the simultaneous equilibria and allows for the effect of ionic strength in the solution.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

Curriculum

Keywords (Subject):

Equilibrium

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History

  • Received: August 03, 2009

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