Thermochemical Radii of Complex Ions

Helen K. Roobottom and H. Donald B. Jenkins
Department of Chemistry, University of Warwick, Coventry CV4 7AL, West Midlands, UK
Jack Passmore
Department of Chemistry, University of New Brunswick, Fredericton, NB, E3B 6E2, Canada
Leslie Glasser
Centre for Molecular Design, Department of Chemistry, University of Witwatersrand, Johannesburg, P.O. WITS 2050, South Africa
J. Chem. Educ., 1999, 76 (11), p 1570
DOI: 10.1021/ed076p1570
Publication Date (Web): November 1, 1999

Abstract

Using rectilinear correlations of lattice energy with the inverse cubic root of the volume per molecule of complex salts of type MX (1:1), M2X (2:1), and MX2 (1:2) we have generated a comprehensive self-consistent tabulation of more than 400 thermochemical radii for complex ions. These radii can be used in the Kapustinskii equation to generate lattice energies and also as ion size parameters.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Pedagogy):

Textbooks / Reference Books

Keywords (Subject):

Computational Chemistry

Citing Articles

View all 19 citing articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 19 ACS Journal articles (5 most recent appear below).

Tools

SciFinder Links

SciFinder subscribers:  Click to sign in | Not a SciFinder subscriber? Learn more at www.cas.org

Explore by:


History

  • Received: August 03, 2009

Recommend & Share

  • Share on ACS NetworkACS Network
  • Add to FacebookFacebook
  • Tweet ThisTweet This
  • Add to CiteULikeCiteULike
  • Add to NewsvineNewsvine
  • Digg ThisDigg This
  • Add to DeliciousDelicious

Related Content