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Gold Chemistry: The Aurophilic Attraction
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Abstract
The aurophilic attraction or aurophilia is an empirically found phenomenon consisting of a weak attractive force between gold atoms that is, nevertheless, as strong as hydrogen bonds. This phenomenon produces, inter alia, shorter intramolecular and intermolecular distances than expected between gold centers and unexpected geometries.
Keywords (Audience):
Second-Year UndergraduateKeywords (Domain):
Inorganic ChemistryKeywords (Subject):
OrganometallicsCiting Articles
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This article has been cited by 17 ACS Journal articles (5 most recent appear below).

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Michael J. Katz, Taramatee Ramnial, Hua-Zhong Yu and Daniel B. LeznoffJournal of the American Chemical Society2008 130 (32), 10662-10673Four polymorphic forms of the complex Zn[Au(CN)2]2 have been synthesized and both structurally and spectroscopically characterized. In each of the four polymorphs, a zinc center in a tetrahedral geometry with a Au(CN)2− unit at each tetrahedral vertex is ...
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- Received: August 03, 2009
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