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Ruthenium Complexes with h1-Organic Ligands: An Advanced Undergraduate Inorganic/Organometallic Chemistry Experiment
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Abstract
This experiment involves interconversions of carbene and alkenyl ligands, important monohapto ligands which are often met in an advanced undergraduate organometallic chemistry course. References are provided to extend the experiment to include alkynyl and vinylidene ligands.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Organic ChemistryKeywords (Pedagogy):
Hands-On Learning / ManipulativesKeywords (Subject):
OrganometallicsCiting Articles
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This article has been cited by 6 ACS Journal articles (5 most recent appear below).
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J. H. Niewahner and Keith A. WaltersJournal of Chemical Education2007 84 (4), 702Laboratory instructions for a glove box experiment involving the synthesis of the compound bis(1,2-dimethylimidazole)copper(I) hexafluorophosphate are given. This synthesis (modified from a previous literature article) can be completed in a four-hour lab ...
A Solid-State NMR Experiment: Analysis of Local Structural Environments in Phosphate Glasses
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Hellmut Eckert and Karin Meise-Gresch , Stanley E. Anderson and David SaikiJournal of Chemical Education2004 81 (7), 1034The solid state 31P NMR wideline spectra of a series of student-prepared sodium phosphate glasses can easily be measured using a standard multinuclear FTNMR spectrometer available in many chemistry departments. The observed spectra can be simulated by ...
Syntheses and Characterization of Ruthenium(II) Tetrakis(Pyridine) Complexes. An Advanced Coordination Chemistry Experiment or Mini-Project
Benjamin J. CoeJournal of Chemical Education2004 81 (5), 718Syntheses and Characterization of Ruthenium(II) Tetrakis(Pyridine) Complexes. An Advanced Coordination Chemistry Experiment or Mini-Project
Benjamin J. CoeJournal of Chemical Education2004 81 (5), 718This experiment involves the syntheses of several coordination complexes of ruthenium(II) and their characterization by using various spectroscopic and spectrometric techniques. Because ruthenium is a precious metal all of the reactions are carried out on ...
Synthesis, Kinetics, and Thermodynamics: An Advanced Laboratory Investigation of the Cis-Trans Isomerization of Mo(CO)4(PR3)2
Kim E. Mooney , Ashfaq A. BengaliJournal of Chemical Education2003 80 (9), 1044Synthesis, Kinetics, and Thermodynamics: An Advanced Laboratory Investigation of the Cis-Trans Isomerization of Mo(CO)4(PR3)2
Kim E. Mooney , Ashfaq A. BengaliJournal of Chemical Education2003 80 (9), 1044An advanced laboratory experiment that requires students to thoroughly investigate the kinetics, thermodynamics, and the mechanism of the cis–trans isomerization of Mo(CO)4(PR3)2 (R = Et, n-butyl) is presented. The students synthesize the cis complex and ...
Ruthenium Vinylidene and Acetylide Complexes. An Advanced Undergraduate Multi-technique Inorganic/Organometallic Chemistry Experiment
Andrew M. McDonagh , Geoffrey J. Deeble , Steph Hurst , Marie P. Cifuentes and Mark G. HumphreyJournal of Chemical Education2001 78 (2), 232Ruthenium Vinylidene and Acetylide Complexes. An Advanced Undergraduate Multi-technique Inorganic/Organometallic Chemistry Experiment
Andrew M. McDonagh , Geoffrey J. Deeble , Steph Hurst , Marie P. Cifuentes and Mark G. HumphreyJournal of Chemical Education2001 78 (2), 232This experiment describes the isolation and characterization of complexes containing examples of two important monohapto ligands, namely vinylidene and alkynyl ligands. The former is a tautomer of acetylene that has minimal (10-10 s) existence as an ...
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- Received: August 03, 2009
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