Hydrogen Bonds Involving Transition Metal Centers Acting As Proton Acceptors

Antonio Martín
Universidad de Zaragoza - C. S. I. C., Departamento de Quimica Inorganica - Instituto de Ciencia de Materiales de Aragon, E-50009 Cuidad Universitaria, Zaragoza, SPAIN
J. Chem. Educ., 1999, 76 (4), p 578
DOI: 10.1021/ed076p578
Publication Date (Web): April 1, 1999

Abstract

A short review of the most remarkable results which have recently reported M----H-X hydrogen bonds, along with a systematization of their structural and spectroscopic properties, is provided in this paper. These M----H interactions are substantially different from the "agostic" M----H ones, and their differences are commented on, setting up criteria that permit their clear differentiation in order to avoid some of the misidentifications that occurred in the past.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Subject):

Coordination Compounds

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History

  • Received: August 03, 2009

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