Spreadsheet Investigation of First-Order Kinetics

Glenn V. Lo
Department of Physical Sciences, Nicholls State University, Thibodaux, LA 70310
J. Chem. Educ., 2000, 77 (4), p 532
DOI: 10.1021/ed077p532
Publication Date (Web): April 1, 2000

Abstract

Spreadsheet exercises designed for in-depth examination of the first-order rate law are described. The exercises illustrate two main approaches for analyzing first-order rate data and allow students to examine how they are affected by systematic and random errors. One method involves plotting the logarithm of a property proportional to the concentration of the species undergoing exponential decay, and the other is the method of Guggenheim. The exercises aim to provide a sound foundation for the students to make intelligent decisions with regard to data acquisition and analysis.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

Physical Chemistry

Keywords (Feature):

Computer Bulletin Board

Keywords (Pedagogy):

Computer-Based Learning

Keywords (Subject):

Kinetics

Citing Articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 8 ACS Journal articles (5 most recent appear below).

  • Cover Image

    Consecutive C60 Fullerene Dissociation from Ir(η2-C60)(CO)(Cl)(PPh3)2 and the Oxidative Addition of Benzene

    Tamara Félix and José E. Cortés-Figueroa
    Journal of Chemical Education2010 87 (4), 426-428
    • Consecutive C60 Fullerene Dissociation from Ir(η2-C60)(CO)(Cl)(PPh3)2 and the Oxidative Addition of Benzene

      Tamara Félix and José E. Cortés-Figueroa
      Journal of Chemical Education2010 87 (4), 426-428

      This laboratory activity is a mechanistic exploration of the interactions between electronically deficient organometallic compounds and solvent molecules. Simple kinetics experiments designed to explore the mechanism of C60 fullerene−benzene exchange on ...

  • Cover Image

    [60]Fullerene Displacement from (Dihapto-Buckminster-Fullerene) Pentacarbonyl Tungsten(0): An Experiment for the Inorganic Chemistry Laboratory, Part II

    Deborah A. Moore-Russo , José E. Cortés-Figueroa
    Journal of Chemical Education2006 83 (11), 1670
    • [60]Fullerene Displacement from (Dihapto-Buckminster-Fullerene) Pentacarbonyl Tungsten(0): An Experiment for the Inorganic Chemistry Laboratory, Part II

      Deborah A. Moore-Russo , José E. Cortés-Figueroa
      Journal of Chemical Education2006 83 (11), 1670

      The kinetics experiments on the ligand-C60 exchange reactions on (dihapto-[60]fullerene) pentacarbonyl tungsten(0), (η2-C60)W(CO)5, form an educational activity for the inorganic chemistry laboratory that promotes graphical thinking as well as the ...

  • Cover Image

    Promoting Graphical Thinking: Using Temperature and a Graphing Calculator To Teach Kinetics Concepts

    Deborah A. Moore-Russo , José E. Cortés-Figueroa , Mark Case
    Journal of Chemical Education2004 81 (1), 69
    • Promoting Graphical Thinking: Using Temperature and a Graphing Calculator To Teach Kinetics Concepts

      Deborah A. Moore-Russo , José E. Cortés-Figueroa , Mark Case
      Journal of Chemical Education2004 81 (1), 69

      A Calculator-Based Laboratory (CBL) System, a graphing calculator, and a cooling piece of metal are used in a classroom demonstration to teach key concepts of a first-order chemical reaction.

  • Cover Image

    Peer-Reviewed JCE WebWare

    William F. Coleman , Edward W. Fedosky
    Journal of Chemical Education2004 81 (1), 159
    • Peer-Reviewed JCE WebWare

      William F. Coleman , Edward W. Fedosky
      Journal of Chemical Education2004 81 (1), 159

      To celebrate the official initiation of the Journal of Chemical Education Digital Library, this month we add “Kinetica: An Excel Program To Simulate or Analyze Kinetic Data” to our collection of 20 peer-reviewed WebWare programs.

  • Cover Image

    Kinetica: An Excel Program To Simulate or Analyze Kinetic Data

    Leonel R. Vera , Pedro A. Ortega and Miguel Guzmán
    Journal of Chemical Education2004 81 (1), 159
    • Kinetica: An Excel Program To Simulate or Analyze Kinetic Data

      Leonel R. Vera , Pedro A. Ortega and Miguel Guzmán
      Journal of Chemical Education2004 81 (1), 159

      Instructors or students can generate simulated kinetic data using parameters they specify, or using parameters randomized by Kinetica. The data set that is generated may then be exported for use in exercises, homework, and exams, or may be analyzed ...

Tools

SciFinder Links

SciFinder subscribers:  Click to sign in | Not a SciFinder subscriber? Learn more at www.cas.org

Explore by:


History

  • Received: August 03, 2009

Recommend & Share

  • Share on ACS NetworkACS Network
  • Add to FacebookFacebook
  • Tweet ThisTweet This
  • Add to CiteULikeCiteULike
  • Add to NewsvineNewsvine
  • Digg ThisDigg This
  • Add to DeliciousDelicious

Related Content