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Self-Assembly of Microporous Thiogermanate Frameworks

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Mark J. MacLachlan , Robert W. J. Scott , Geoffrey A. Ozin and Douglas F. McIntosh

Department of Chemistry, University of Toronto, Toronto, ON M5S 3H6, Canada

J. Chem. Educ., 2000, 77 (5), p 630

DOI: 10.1021/ed077p630

Publication Date (Web): May 1, 2000

Section:

History, Education, and Documentation

Abstract

A safe undergraduate laboratory experiment involving the synthesis of microporous metal germanium sulfide materials under aqueous, room-temperature conditions is described. It introduces students to the synthetic methods of self-assembly and solid-state chemistry. The products are characterized by powder X-ray diffraction and vibrational spectroscopy.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Solid State Chemistry

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This article has been cited by 2 ACS Journal articles (2 most recent appear below).

The Use of Cyclic Voltammetry To Probe the Passivation of Electrode Surfaces by Well-Ordered Self-Assembly and Langmuir–Blodgett Films. An Advanced Undergraduate Laboratory Experiment in Surface Science and Nanomaterials Chemistry
Ana Villares , Gorka Pera and Ignacio Giner , Pilar Cea and María C. López , Santiago Martín
Journal of Chemical Education2009 86 (6), 723
- The Use of Cyclic Voltammetry To Probe the Passivation of Electrode Surfaces by Well-Ordered Self-Assembly and Langmuir–Blodgett Films. An Advanced Undergraduate Laboratory Experiment in Surface Science and Nanomaterials Chemistry
  Ana Villares , Gorka Pera and Ignacio Giner , Pilar Cea and María C. López , Santiago Martín
  Journal of Chemical Education2009 86 (6), 723
  An advanced undergraduate laboratory experiment is described in which the students use cyclic voltammetry (CV) as an electrochemical tool to probe the passivation of electrode surfaces covered by well-ordered self-assembly and Langmuir–Blodgett films. ...
  Abstract | Hi-Res PDF | PDF w/ Links
Platinum Chalcogenido MCM-41 Analogues. High Hexagonal Order in Mesostructured Semiconductors Based on Pt²⁺ and [Ge₄Q₁₀]^4- (Q = S, Se) and [Sn₄Se₁₀]^4- Adamantane Clusters
Pantelis N. Trikalitis, Krishnaswamy K. Rangan, and Mercouri G. Kanatzidis
Journal of the American Chemical Society2002 124 (11), 2604-2613
- Platinum Chalcogenido MCM-41 Analogues. High Hexagonal Order in Mesostructured Semiconductors Based on Pt²⁺ and [Ge₄Q₁₀]^4- (Q = S, Se) and [Sn₄Se₁₀]^4- Adamantane Clusters
  Pantelis N. Trikalitis, Krishnaswamy K. Rangan, and Mercouri G. Kanatzidis
  Journal of the American Chemical Society2002 124 (11), 2604-2613
  Highly periodic hexagonal honeycombs of platinumgermanium chalcogenide and platinumtin selenide frameworks were prepared by linking corresponding [Ge4Q10]4- (Q = S, Se) and [Sn4Se10]4- clusters with Pt2+ ions. The non-oxidic honeycombs designated as Cn...
  Abstract | Full Text HTML | Hi-Res PDF

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Received: August 03, 2009

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Self-Assembly of Microporous Thiogermanate Frameworks