S is for Entropy. U is for Energy. What Was Clausius Thinking?

Irmgard K. Howard
Department of Chemistry, Houghton College, Houghton, NY 14744
J. Chem. Educ., 2001, 78 (4), p 505
DOI: 10.1021/ed078p505
Publication Date (Web): April 1, 2001

Abstract

In the development of thermodynamics, 19th-century scientist Rudolf Clausius devised mathematical equations with which to describe the actions and relationships of heat and work. This paper traces his thinking from his 1850 publication on "The Moving Force of Heat and the Laws Which May Be Deduced Therefrom" to the 1879 English edition of his textbook, The Mechanical Theory of Heat, particularly noting his ideas about parallel concepts of energy and entropy.

Keywords (Audience):

Continuing Education

Keywords (Domain):

History / Philosophy

Keywords (Subject):

Thermodynamics

Citing Articles

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This article has been cited by 4 ACS Journal articles (4 most recent appear below).

  • Cover Image

    Teaching Entropy Analysis in the First-Year High School Course and Beyond

    Thomas H. Bindel
    Journal of Chemical Education2004 81 (11), 1585
    • Teaching Entropy Analysis in the First-Year High School Course and Beyond

      Thomas H. Bindel
      Journal of Chemical Education2004 81 (11), 1585

      A 16-day teaching unit is presented that develops chemical thermodynamics at the introductory high school level and beyond from exclusively an entropy viewpoint referred to as entropy analysis. Many concepts are presented, such as: entropy, spontaneity, ...

  • Cover Image

    A Compilation of the Seminal Works of R. Clausius

    J. C. Jones
    Journal of Chemical Education2003 80 (12), 1383
    • A Compilation of the Seminal Works of R. Clausius

      J. C. Jones
      Journal of Chemical Education2003 80 (12), 1383

      The author adds his comments on the 1867 English translation of Clausius’ nine seminal memoirs.

  • Cover Image

    Three Forms of Energy

    Sigthór Pétursson
    Journal of Chemical Education2003 80 (7), 776
    • Three Forms of Energy

      Sigthór Pétursson
      Journal of Chemical Education2003 80 (7), 776

      The paper, which is intended for students and teachers of general and physical chemistry, presents questions relating to thermal, mechanical, and gas expansion processes and works out the energy involved. The examples illustrate the physical meaning of ...

  • Cover Image

    H Is for Enthalpy, Thanks to Heike Kamerlingh Onnes and Alfred W. Porter

    Irmgard K. Howard
    Journal of Chemical Education2002 79 (6), 697
    • H Is for Enthalpy, Thanks to Heike Kamerlingh Onnes and Alfred W. Porter

      Irmgard K. Howard
      Journal of Chemical Education2002 79 (6), 697

      During the 19th century the letter H sometimes represented heat, but the designation of enthalpy was placed into the scientific literature in 1909 by J. P. Dalton and credited by him to Heike Kamerlingh Onnes. In 1922 Alfred W. Porter formally proposed ...

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History

  • Received: August 03, 2009

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