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Electronic Structure Principles and Atomic Shell Structure
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Abstract
Hardness and polarizability are associated with easily discernible atomic shell structures across the periodic table. In a given period the noble gas atom is the hardest and the least polarizable, as expected from its exceptional stability vis-a-vis the principles of maximum hardness and minimum polarizability. The electrophilicity index also exhibits periodicity.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Physical ChemistryKeywords (Subject):
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This article has been cited by 9 ACS Journal articles (5 most recent appear below).

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Minimum Polarizability Principle Applied to Lowest Energy Isomers of Some Gaseous All-Metal Clusters
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Chao-Yong Mang, Xia Zhao, Li-Xian He, Cai-Ping Liu, and Ke-Chen WuThe Journal of Physical Chemistry A2008 112 (7), 1661-1665In comparison with the minimum energy criterion as an indicator of the most stable state, the minimum polarizability and maximum hardness principles have been examined to describe the relative stability of various isomers of nine gaseous all-metal ...

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Pratim Kumar Chattaraj and Debesh Ranjan RoyChemical Reviews2007 107 (9), PR46-PR74Update 1 of: Electrophilicity Index
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Electronic Structure Principles and Aromaticity
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P. K. Chattaraj , U. Sarkar and D. R. RoyJournal of Chemical Education2007 84 (2), 354Principles of minimum energy, minimum polarizability, minimum electrophilicity, and maximum hardness dictate that the aromatic molecules are associated with low energy, low polarizability, low electrophilicity, and high hardness values. The antiaromatic ...

Electrophilicity Index
Pratim Kumar Chattaraj, Utpal Sarkar, and Debesh Ranjan RoyChemical Reviews2006 106 (6), 2065-2091Electrophilicity Index
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- Received: August 03, 2009
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