Letter
Have Orbitals Really Been Observed?
Abstract
Expelling false claims regarding the observation of orbitals.
Keywords (Audience):
General PublicKeywords (Domain):
Chemical Education ResearchKeywords (Feature):
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Computational ChemistryCiting Articles
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This article has been cited by 3 ACS Journal articles (3 most recent appear below).

Shake For Sigma, Pray For Pi: Classroom Orbital Overlap Analogies
Andrew P. DicksJournal of Chemical Education2011 88 (4), 426-427Shake For Sigma, Pray For Pi: Classroom Orbital Overlap Analogies
Andrew P. DicksJournal of Chemical Education2011 88 (4), 426-427An introductory organic classroom demonstration is discussed where analogies are made between common societal hand contact and covalent bond formation. A handshake signifies creation of a σ bond (“head-on” orbital overlap), whereas the action of praying ...

Two Equivalent eg Orbitals for the Discussion of Bonding in Octahedral Complexes
Kai Brandhorst and Jörg Grunenberg , Matthias TammJournal of Chemical Education2008 85 (12), 1692Two Equivalent eg Orbitals for the Discussion of Bonding in Octahedral Complexes
Kai Brandhorst and Jörg Grunenberg , Matthias TammJournal of Chemical Education2008 85 (12), 1692A new set of d orbitals, constructed as a linear combination of the omnipresent set of dxy, dyz, dxz, dx2–y2, and dz2 orbitals, is suitable for the discussion of octahedral transition-metal complexes. The main feature of the newly derived set orbitals ...

The Particle Inside a Ring: A Two-Dimensional Quantum Problem Visualized by Scanning Tunneling Microscopy
Mark D. EllisonJournal of Chemical Education2008 85 (9), 1282The Particle Inside a Ring: A Two-Dimensional Quantum Problem Visualized by Scanning Tunneling Microscopy
Mark D. EllisonJournal of Chemical Education2008 85 (9), 1282The one-dimensional particle-in-a-box model used to introduce quantum mechanics to students suffers from a tenuous connection to a real physical system. This article presents a two-dimensional model, the particle confined within a ring, that directly ...
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History
- Received: August 03, 2009
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