Have Orbitals Really Been Observed?

Eric R. Scerri
Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569
J. Chem. Educ., 2002, 79 (3), p 310
DOI: 10.1021/ed079p310.1
Publication Date (Web): March 1, 2002

Abstract

Expelling false claims regarding the observation of orbitals.

Keywords (Audience):

General Public

Keywords (Domain):

Chemical Education Research

Keywords (Feature):

Letters

Keywords (Pedagogy):

Misconceptions / Discrepant Events

Keywords (Subject):

Computational Chemistry

Citing Articles

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This article has been cited by 3 ACS Journal articles (3 most recent appear below).

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      Andrew P. Dicks
      Journal of Chemical Education2011 88 (4), 426-427

      An introductory organic classroom demonstration is discussed where analogies are made between common societal hand contact and covalent bond formation. A handshake signifies creation of a σ bond (“head-on” orbital overlap), whereas the action of praying ...

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    Two Equivalent eg Orbitals for the Discussion of Bonding in Octahedral Complexes

    Kai Brandhorst and Jörg Grunenberg , Matthias Tamm
    Journal of Chemical Education2008 85 (12), 1692
    • Two Equivalent eg Orbitals for the Discussion of Bonding in Octahedral Complexes

      Kai Brandhorst and Jörg Grunenberg , Matthias Tamm
      Journal of Chemical Education2008 85 (12), 1692

      A new set of d orbitals, constructed as a linear combination of the omnipresent set of dxy, dyz, dxz, dx2–y2, and dz2 orbitals, is suitable for the discussion of octahedral transition-metal complexes. The main feature of the newly derived set orbitals ...

  • Cover Image

    The Particle Inside a Ring: A Two-Dimensional Quantum Problem Visualized by Scanning Tunneling Microscopy

    Mark D. Ellison
    Journal of Chemical Education2008 85 (9), 1282
    • The Particle Inside a Ring: A Two-Dimensional Quantum Problem Visualized by Scanning Tunneling Microscopy

      Mark D. Ellison
      Journal of Chemical Education2008 85 (9), 1282

      The one-dimensional particle-in-a-box model used to introduce quantum mechanics to students suffers from a tenuous connection to a real physical system. This article presents a two-dimensional model, the particle confined within a ring, that directly ...

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History

  • Received: August 03, 2009

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