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129Xe NMR of Zeolite NaY in the Inorganic Chemistry Laboratory

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Tanja Pietraß

Department of Chemistry, New Mexico Tech, Socorro, NM 87801

J. Chem. Educ., 2002, 79 (4), p 492

DOI: 10.1021/ed079p492

Publication Date (Web): April 1, 2002

Section:

History, Education, and Documentation

Abstract

¹²⁹Xe NMR spectroscopy of xenon physisorbed in commercially available zeolite NaY is introduced as an experiment suitable for the inorganic chemistry laboratory in the senior year. The integration of concepts from inorganic and physical chemistry (ideal gas law, gas adsorption, solid state structure, porous materials, NMR spectroscopy) make this experiment also suitable for an integrated laboratory approach. The chemical shift of ¹²⁹Xe at different loadings in the α-cages of zeolite NaY is used to derive the intrinsic chemical shift by extrapolation to zero loading.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Gases

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