The Microscopic Statement of the Second Law of Thermodynamics

Igor Novak
Department of Chemistry, National University of Singapore, Singapore 117543
J. Chem. Educ., 2003, 80 (12), p 1428
DOI: 10.1021/ed080p1428
Publication Date (Web): December 1, 2003

Abstract

The teaching of basic concepts in thermodynamics is described from the microscopic point of view, that is, using only particle energies and level populations as descriptors.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Curriculum

Keywords (Subject):

Statistical Mechanics

Citing Articles

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This article has been cited by 5 ACS Journal articles (5 most recent appear below).

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    Microscopic Description of Le Châtelier's Principle

    Igor Novak
    Journal of Chemical Education2005 82 (8), 1190
    • Microscopic Description of Le Châtelier's Principle

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      The analysis based on microscopic descriptors (energy levels and their populations) is given that provides visualization of free energies and conceptual rationalization of Le Châtelier's principle. The misconception "nature favors equilibrium" is ...

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History

  • Received: August 03, 2009

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