A Photolithography Laboratory Experiment for General Chemistry Students

Thomas C. DeVore and Brian H. Augustine
Department of Chemistry, James Madison University, Harrisonburg, VA 22807
Adora M. Christenson
Human Genome Sciences, Department of Formulation and Stability, Rockford, MD 20850
Gregory W. Corder
Department of Physics, James Madison University, Harrisonburg, VA 22807
J. Chem. Educ., 2003, 80 (2), p 183
DOI: 10.1021/ed080p183
Publication Date (Web): February 1, 2003

Abstract

Photolithography is the primary means of pattern transfer used in the production of a multitude of microfabricated devices, including integrated circuits, microelectromechanical systems, and optoelectronic devices. The underlying photochemical process inherent to lithography is an attractive model system to introduce photochemistry, reaction kinetics, polymer chemistry, and materials science to a broader audience in a general chemistry laboratory setting. We report a second-semester general chemistry experiment in which students design and produce a photomask to pattern a silicon wafer using optical lithography. In addition to substrate patterning, students examine the reaction kinetics of the photobleaching process of the photoresist system using a UV–vis spectrometer operating in the kinetics mode. Both experiments introduce lower-division students to a technologically important industrial chemistry process and aid in understanding the topics of polymer chemistry and photochemistry.

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Domain):

Polymer Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Kinetics

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    Atomic Force Microscopy Analysis of Nanocrystalline Patterns Fabricated Using Micromolding in Capillaries

    Benjamin M. Lyman, Orrin J. Farmer, Ryan D. Ramsey, Samuel T. Lindsey, Stephanie Stout, Adam Robison, Holly J. Moore, and Wesley C. Sanders
    Journal of Chemical Education2012 Article ASAP
    • Atomic Force Microscopy Analysis of Nanocrystalline Patterns Fabricated Using Micromolding in Capillaries

      Benjamin M. Lyman, Orrin J. Farmer, Ryan D. Ramsey, Samuel T. Lindsey, Stephanie Stout, Adam Robison, Holly J. Moore, and Wesley C. Sanders
      Journal of Chemical Education2012 Article ASAP

      A cost-effective, hands-on laboratory exercise is described for demonstrating nanoscale fabrication at non-research-based educational institutions. The laboratory exercise also contains a component involving qualitative and quantitative surface ...

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History

  • Received: August 03, 2009

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