Exactly Solvable Quantum Mechanical Potentials: An Alternative Approach

Jeremy N. Pronchik
Merck & Company, Inc., Rahway, NJ 07065
Brian W. Williams
Department of Chemistry, Bucknell University, Lewisburg, PA 17837
J. Chem. Educ., 2003, 80 (8), p 918
DOI: 10.1021/ed080p918
Publication Date (Web): August 1, 2003

Abstract

An alternative method for finding exactly solvable quantum mechanical potentials is presented and discussed. As examples of this approach, the hydrogenic (Coulomb) radial potential and the anharmonic Pöschl—Teller diatomic potential are derived. The utility of the latter potential is checked by fitting it to published data for the B electronic state of diatomic iodine. This alternative means of finding exactly solvable quantum mechanical potentials should be of interest and use to physical and theoretical chemists.

Keywords (Audience):

Graduate Education / Research

Keywords (Domain):

Physical Chemistry

Keywords (Feature):

Research: Science and Education

Keywords (Subject):

Quantum Chemistry

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

  • Cover Image

    New Potentials for Old: The Darboux Transformation in Quantum Mechanics

    Brian Wesley Williams , Tevye C. Celius
    Journal of Chemical Education2008 85 (4), 576
    • New Potentials for Old: The Darboux Transformation in Quantum Mechanics

      Brian Wesley Williams , Tevye C. Celius
      Journal of Chemical Education2008 85 (4), 576

      The Darboux transformation in quantum mechanics is reviewed at a basic level. Examples of how this transformation leads to exactly solvable potentials related to the "particle in a box" and the harmonic oscillator are shown in detail. The connection ...

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History

  • Received: August 03, 2009

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