Don't Be Tricked by Your Integrated Rate Plot: Pitfalls of Using Integrated Rate Plots

Gabor Lente
Department of Inorganic and Analytical Chemistry, University of Debrecen, H-4010 Debrecen, Hungary
J. Chem. Educ., 2004, 81 (1), p 32
DOI: 10.1021/ed081p32.1
Publication Date (Web): January 1, 2004

Abstract

Problems with linearizing the integrated rate law.

Keywords (Audience):

High School / Introductory Chemistry

Keywords (Feature):

Letters

Keywords (Pedagogy):

Textbooks / Reference Books

Keywords (Subject):

Kinetics

Citing Articles

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This article has been cited by 2 ACS Journal articles (2 most recent appear below).

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    Journal of Chemical Education2008 85 (1), 112
    • A Simple Rate Law Experiment Using a Custom-Built Isothermal Heat Conduction Calorimeter

      Lars Wadsö , Xi Li
      Journal of Chemical Education2008 85 (1), 112

      Most processes (whether physical, chemical, or biological) produce or consume heat: measuring thermal power (the heat production rate) is therefore a typical method of studying processes. Here we describe the design of a simple isothermal heat conduction ...

  • Cover Image

    First-Order or Second-Order Kinetics? A Monte Carlo Answer

    Joel Tellinghuisen
    Journal of Chemical Education2005 82 (11), 1709
    • First-Order or Second-Order Kinetics? A Monte Carlo Answer

      Joel Tellinghuisen
      Journal of Chemical Education2005 82 (11), 1709

      In chemical kinetics, data for the concentration [A] as a function of time can be analyzed by least-squares fitting to the appropriate expression for the integrated rate law. The problem of discriminating between first and second order in such analyses is ...

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History

  • Received: August 03, 2009

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