Valence, Covalence, Hypervalence, Oxidation State, and Coordination Number

Derek W. Smith
Department of Chemistry, University of Waikato, Hamilton, New Zealand
J. Chem. Educ., 2005, 82 (8), p 1202
DOI: 10.1021/ed082p1202
Publication Date (Web): August 1, 2005

Abstract

It is argued that the terms valence, covalence, hypervalence, oxidation state, and coordination number are often confused and misused in the literature. It is recommended that use of the term valence, and its associated terminology, should be restricted to simple molecular main group substances and to some oxoacids and derivatives, but avoided in both main group and transition element coordination chemistry.

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Domain):

History / Philosophy

Keywords (Pedagogy):

Misconceptions / Discrepant Events

Keywords (Subject):

Coordination Compounds

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History

  • Received: August 03, 2009

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