Demonstrating Energy Migration in Coupled Oscillators. A Central Concept in the Theory of Unimolecular Reactions

Ronald E. Marcotte
Department of Chemistry, Texas A&M University–Kingsville, Kingsville, TX 78363
James A. Zimmerman
Department of Chemistry, Southwest Missouri State University, Springfield, MO 65804-0089
J. Chem. Educ., 2005, 82 (10), p 1530
DOI: 10.1021/ed082p1530
Publication Date (Web): October 1, 2005

Abstract

This physical chemistry lecture demonstration is designed to aid the understanding of intramolecular energy transfer processes as part of the presentation of the theory of unimolecular reaction rates. Coupled pendulums are used to show the rate of migration of energy between oscillators under resonant and nonresonant conditions with varying degrees of coupling and how that relates to chemical reaction.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Demonstrations

Keywords (Feature):

JCE DigiDemos: Tested Demonstrations

Keywords (Pedagogy):

Analogies / Transfer

Keywords (Subject):

Enrichment / Review Materials

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History

  • Received: August 03, 2009

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