Fractional Distillation of Air and Other Demonstrations with Condensed Gases

Maria Oliver-Hoyo and William L. Switzer III
Department of Chemistry, North Carolina State University, Raleigh, NC 27695
Robert Eierman
Department of Chemistry, University of Wisconsin–Eau Claire, Eau Claire, WI 54701
J. Chem. Educ., 2005, 82 (2), p 251
DOI: 10.1021/ed082p251
Publication Date (Web): February 1, 2005

Abstract

This demonstration builds upon the commonly performed liquefaction of air not only to show the presence of nitrogen and oxygen, but also the presence of two other components, carbon dioxide and water. Several extensions are suggested: one to show boiling point elevation in solution and another to show the elevation of both boiling point and sublimation point with pressure. No special apparatus is required permitting presentations to audiences in a variety of settings. These demonstrations give the opportunity to discuss properties of gases, solution chemistry, and phase equilibria. Special emphasis is given to the conceptual explanations of the processes involved.

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Keywords (Audience):

High School / Introductory Chemistry

Keywords (Domain):

Demonstrations

Keywords (Feature):

JCE DigiDemos: Tested Demonstrations

Keywords (Subject):

Gases

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History

  • Received: August 03, 2009

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