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The Origin of the 18-Electron Rule

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William B. Jensen

Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221-0172

J. Chem. Educ., 2005, 82 (1), p 28

DOI: 10.1021/ed082p28

Publication Date (Web): January 1, 2005

Section:

History, Education, and Documentation

Abstract

In response to a reader query, this article traces the origins of the 18-electron rule back to a 1921 paper by Irving Langmuir.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

History / Philosophy

Keywords (Feature):

Ask the Historian

Keywords (Subject):

Organometallics

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Ambiphilic Reactivity of a Phosphane-Functionalized Cycloheptatrienyl−Cyclopentadienyl Zirconium Sandwich Complex
Susanne Büschel, Constantin Daniliuc, Peter G. Jones and Matthias Tamm
Organometallics2010 29 (3), 671-675
- Ambiphilic Reactivity of a Phosphane-Functionalized Cycloheptatrienyl−Cyclopentadienyl Zirconium Sandwich Complex
  Susanne Büschel, Constantin Daniliuc, Peter G. Jones and Matthias Tamm
  Organometallics2010 29 (3), 671-675
  The reactions of the phosphane-functionalized cycloheptatrienyl−cyclopentadienyl sandwich complex [(η7-C7H7)Zr(η5-C5H4PiPr2)] (1) with selenium, [(tht)AuCl] (tht = tetrahydrothiophene) and [(η6-C7H8)W(CO)3] (C7H8 = 1,3,5-cycloheptatriene) afford the ...
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