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Nontypical Brønsted Acids and Bases
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Abstract
The article refers to redox systems exhibiting some uncommon properties as non-monotonic or segmented pH changes affected by addition of some reagents. All the data were obtained on the basis of simulated titrations made according to the iterative computer program MINUIT. The calculation procedure, when made according to the generalized approach suggested by the author, enables one to reconstruct any analytical prescription and apply all attainable physicochemical data involved.
Keywords (Audience):
Upper-Division UndergraduateKeywords (Domain):
Analytical ChemistryKeywords (Subject):
Acids / BasesCiting Articles
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This article has been cited by 1 ACS Journal articles (1 most recent appear below).
pH-Static Titration: A Quasistatic Approach
Tadeusz Michalowski , Marcin Toporek and Maciej RymanowskiJournal of Chemical Education2007 84 (1), 142pH-Static Titration: A Quasistatic Approach
Tadeusz Michalowski , Marcin Toporek and Maciej RymanowskiJournal of Chemical Education2007 84 (1), 142A concise presentation of pH-static titration is followed by examples of some electrolytic systems where this technique can be applied. The equilibrium analysis explains quantitatively all the processes involved. Some new possibilities of the method, for ...
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History
- Received: August 03, 2009
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