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How to Compute Labile Metal–Ligand Equilibria
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Abstract
The properties of labile metal–ligand equilibria can be calculated readily by using the concept of a ligand function, analogous to the proton function of acid–base behavior. Use of the ligand function allows one to have a computer perform the tedious iterations, thereby bypassing the traditional trial-and-error method of solving equilibrium problems. The method is also applicable to mixed-ligand complexes.
Keywords (Domain):
Analytical ChemistryKeywords (Pedagogy):
Computer-Based LearningKeywords (Subject):
EquilibriumCiting Articles
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This article has been cited by 1 ACS Journal articles (1 most recent appear below).
Systematic Approach To Calculate the Concentration of Chemical Species in Multi-Equilibrium Problems
Juan José Baeza-Baeza and María Celia García-Álvarez-CoqueJournal of Chemical Education2011 88 (2), 169-173Systematic Approach To Calculate the Concentration of Chemical Species in Multi-Equilibrium Problems
Juan José Baeza-Baeza and María Celia García-Álvarez-CoqueJournal of Chemical Education2011 88 (2), 169-173A general systematic approach is proposed for the numerical calculation of multi-equilibrium problems. The approach involves several steps: (i) the establishment of balances involving the chemical species in solution (e.g., mass balances, charge balance, ...
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- Received: August 03, 2009
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