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Sterically Hindered Square-Planar Nickel(II) Organometallic Complexes: Preparation, Characterization, and Substitution Behavior

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Manuel Martínez , Guillermo Muller , Mercè Rocamora and Carlos Rodríguez

Departament de Química Inorgànica, Facultat de Química, Universitat de Barcelona, Martí I Franquès 1-11, E-08028 Barcelona, Spain

J. Chem. Educ., 2007, 84 (3), p 485

DOI: 10.1021/ed084p485

Publication Date (Web): March 1, 2007

Section:

History, Education, and Documentation

Abstract

The series of experiments proposed for advanced undergraduate students deal with both standard organometallic preparative methods in dry anaerobic conditions and with a kinetic study of the mechanisms operating in the substitution of square-planar complexes. The preparation of organometallic compounds is carried out by transmetallation or oxidative addition procedures. Kinetic experiments deal with the fine tuning in associatively activated substitution processes.

Keywords (Audience):

Upper-Division Undergraduate

Keywords (Domain):

Inorganic Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Coordination Compounds

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