Preparation of Conducting Polymers by Electrochemical Methods and Demonstration of a Polymer Battery

Hiromasa Goto , Hiroyuki Yoneyama , Fumihiro Togashi , Reina Ohta , Akitsu Tsujimoto , Eiji Kita and Ken-ichi Ohshima
College of Engineering Sciences, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8573, Japan
Daniel Rosenberg
Science Center, Harvard University, Cambridge, MA 12138
J. Chem. Educ., 2008, 85 (8), p 1067
DOI: 10.1021/ed085p1067
Publication Date (Web): August 1, 2008

Abstract

The electrochemical polymerization of aniline and pyrrole, and demonstrations of electrochromism and the polymer battery effect, are presented as demonstrations suitable for high school and introductory chemistry at the university level. These demonstrations promote student interest in the electrochemical preparation of conducting polymers, where the doping and dedoping processes can be readily understood from the vivid electrochromism displayed by these two polymers.

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Domain):

Analytical Chemistry

Keywords (Feature):

JCE DigiDemos: Tested Demonstrations

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Aromatic Compounds

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History

  • Received: August 03, 2009

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