Article
A Simple Rate Law Experiment Using a Custom-Built Isothermal Heat Conduction Calorimeter
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Abstract
Most processes (whether physical, chemical, or biological) produce or consume heat: measuring thermal power (the heat production rate) is therefore a typical method of studying processes. Here we describe the design of a simple isothermal heat conduction calorimeter built for use in teaching; we also provide an example of its use in simultaneously determining the rate constant and the reaction enthalpy of the first-order base hydrolysis of propyl parabene.
Keywords (Audience):
Graduate Education / ResearchKeywords (Domain):
Physical ChemistryKeywords (Subject):
Calorimetry / ThermochemistryCiting Articles
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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

Isothermal Titration Calorimetry in the Student Laboratory
Lars Wadsö and Yujing Li, Xi LiJournal of Chemical Education2011 88 (1), 101-105Isothermal Titration Calorimetry in the Student Laboratory
Lars Wadsö and Yujing Li, Xi LiJournal of Chemical Education2011 88 (1), 101-105Isothermal titration calorimetry (ITC) is the measurement of the heat produced by the stepwise addition of one substance to another. It is a common experimental technique, for example, in pharmaceutical science, to measure equilibrium constants and ...
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History
- Received: August 03, 2009
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