Lanthanum (La) and Actinium (Ac) Should Remain in the d-block

Laurence Lavelle
Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90095
J. Chem. Educ., 2008, 85 (11), p 1482
DOI: 10.1021/ed085p1482
Publication Date (Web): November 1, 2008

Abstract

This paper discusses the reasons and implications of placing lanthanum (La) and actinium (Ac) in the f-block and lutetium (Lu) and lawrencium (Lr) in the d-block. The author's conclusion is that placing lanthanum (La) and actinium (Ac) in the f-block results in a less satisfactory presentation of the elements in the periodic table and that lanthanum (La) and actinium (Ac) should remain in the d-block below yttrium (Y) in group 3 (IIIB).

Keywords (Audience):

First-Year Undergraduate / General

Keywords (Domain):

Inorganic Chemistry

Keywords (Feature):

Commentary

Keywords (Pedagogy):

Misconceptions / Discrepant Events

Keywords (Subject):

Actinium

Citing Articles

Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.

This article has been cited by 5 ACS Journal articles (5 most recent appear below).

  • Cover Image

    Theoretical Basis and Correct Explanation of the Periodic System: Review and Update

    W. H. Eugen Schwarz, Ronald L. Rich
    Journal of Chemical Education2010 87 (4), 435-443
    • Theoretical Basis and Correct Explanation of the Periodic System: Review and Update

      W. H. Eugen Schwarz, Ronald L. Rich
      Journal of Chemical Education2010 87 (4), 435-443

      Long-standing questions on the theoretical basis of the periodic system have been answered in recent years. A specific type of periodicity is imposed on all elements by the main groups just before and after the noble gasses. The upper np shells of these ...

  • Cover Image

    Which Elements Belong in Group 3?

    Eric Scerri
    Journal of Chemical Education2009 86 (10), 1188
    • Which Elements Belong in Group 3?

      Eric Scerri
      Journal of Chemical Education2009 86 (10), 1188

      Commentary on a suggestion that the recent trend found in many textbooks, to place lutetium and lawrencium in group 3 of the periodic table instead of lanthanum and actinium, is a mistake.

  • Cover Image

    Response to “Misapplying the Periodic Law”

    Laurence Lavelle
    Journal of Chemical Education2009 86 (10), 1187
    • Response to “Misapplying the Periodic Law”

      Laurence Lavelle
      Journal of Chemical Education2009 86 (10), 1187

      Placing lanthanum and actinium in the f-block is not widely accepted or without problems.

  • Cover Image

    Misapplying the Periodic Law

    William B. Jensen
    Journal of Chemical Education2009 86 (10), 1186
    • Misapplying the Periodic Law

      William B. Jensen
      Journal of Chemical Education2009 86 (10), 1186

      The author comments on a recent recommendation for modifying the placement of La and Ac in the periodic table, feeling that it is based on inconsistent reasoning and contains a serious distortion of the contents of an earlier article dealing with this ...

  • Cover Image

    Response to "The Flyleaf Periodic Table"

    Laurence Lavelle
    Journal of Chemical Education2008 85 (11), 1491
    • Response to "The Flyleaf Periodic Table"

      Laurence Lavelle
      Journal of Chemical Education2008 85 (11), 1491

      Clark and White wonder why the chemistry education community has not uniformly adopted just one form of the periodic table. Part of the answer is that the majority who are silent on this issue do not want to be attacked by the vocal proponents who insist ...

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History

  • Received: August 03, 2009

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