Cart
Article
Diamagnetic Corrections and Pascal's Constants
Hi-Res PDFPurchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
Measured magnetic susceptibilities of paramagnetic substances must typically be corrected for their underlying diamagnetism. This correction is often accomplished by using tabulated values for the diamagnetism of atoms, ions, or whole molecules. These tabulated values can be problematic since many sources contain incomplete and conflicting data. This article presents an explanation for the origin of the diamagnetic correction factors, organized tables of constants compiled from many sources, a simple method for estimating the correct order of magnitude for the diamagnetic correction for any given compound, a clear explanation of how to use the tabulated constants to calculate the diamagnetic susceptibility, and a worked example for the magnetic susceptibility of copper acetate.
Keywords (Audience):
First-Year Undergraduate / GeneralKeywords (Domain):
Inorganic ChemistryKeywords (Pedagogy):
Calculator-Based LearningKeywords (Subject):
Laboratory Computing / InterfacingCiting Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 35 ACS Journal articles (5 most recent appear below).
Synthesis, Molecular and Electronic Structure of UV(O)[N(SiMe3)2]3
Skye Fortier, Jessie L. Brown, Nikolas Kaltsoyannis, Guang Wu, and Trevor W. HaytonInorganic Chemistry2012 51 (3), 1625-1633Synthesis, Molecular and Electronic Structure of UV(O)[N(SiMe3)2]3
Skye Fortier, Jessie L. Brown, Nikolas Kaltsoyannis, Guang Wu, and Trevor W. HaytonInorganic Chemistry2012 51 (3), 1625-1633Addition of 1 equiv of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) to U(NR2)3 in hexanes affords U(O)(NR2)3 (2), which can be isolated in 73% yield. Complex 2 is a rare example of a terminal U(V) oxo complex. In contrast, addition of 1 equiv of Me3NO to ...
Reduction of Terphenyl Co(II) Halide Derivatives in the Presence of Arenes: Insertion of Co(I) into a C–F Bond
Hao Lei, James C. Fettinger, and Philip P. PowerInorganic Chemistry2012 51 (3), 1821-1826Reduction of Terphenyl Co(II) Halide Derivatives in the Presence of Arenes: Insertion of Co(I) into a C–F Bond
Hao Lei, James C. Fettinger, and Philip P. PowerInorganic Chemistry2012 51 (3), 1821-1826Reduction of [(3,5-iPr2-Ar*)Co(μ-Cl)]2 (3,5-iPr2-Ar* = -C6H-2,6-(C6H2-2,4,6-iPr3)2-3,5-iPr2) with KC8 in the presence of various arene molecules resulted in the formation of a series of terphenyl stabilized Co(I) half-sandwich complexes (3,5-iPr2-Ar*)Co(η...
Copper(II) Carboxylate Dimers Prepared from Ligands Designed to Form a Robust π···π Stacking Synthon: Supramolecular Structures and Molecular Properties
Daniel L. Reger, Agota Debreczeni, and Mark D. Smith , Julia Jezierska , Andrew OzarowskiInorganic Chemistry2012 51 (2), 1068-1083Copper(II) Carboxylate Dimers Prepared from Ligands Designed to Form a Robust π···π Stacking Synthon: Supramolecular Structures and Molecular Properties
Daniel L. Reger, Agota Debreczeni, and Mark D. Smith , Julia Jezierska , Andrew OzarowskiInorganic Chemistry2012 51 (2), 1068-1083The reactions of bifunctional carboxylate ligands (1,8-naphthalimido)propanoate, (LC2–), (1,8-naphthalimido)ethanoate, (LC1–), and (1,8-naphthalimido)benzoate, (LC4–) with Cu2(O2CCH3)4(H2O)2 in methanol or ethanol at room temperature lead to the formation ...
The Series of Molecular Conductors and Superconductors ET4[AFe(C2O4)3]·PhX (ET = bis(ethylenedithio)tetrathiafulvalene; (C2O4)2– = oxalate; A+ = H3O+, K+; X = F, Cl, Br, and I): Influence of the Halobenzene Guest Molecules on the Crystal Structure and Superconducting Properties
Eugenio Coronado, Simona Curreli, Carlos Giménez-Saiz, and Carlos J. Gómez-GarcíaInorganic Chemistry2012 51 (2), 1111-1126The Series of Molecular Conductors and Superconductors ET4[AFe(C2O4)3]·PhX (ET = bis(ethylenedithio)tetrathiafulvalene; (C2O4)2– = oxalate; A+ = H3O+, K+; X = F, Cl, Br, and I): Influence of the Halobenzene Guest Molecules on the Crystal Structure and Superconducting Properties
Eugenio Coronado, Simona Curreli, Carlos Giménez-Saiz, and Carlos J. Gómez-GarcíaInorganic Chemistry2012 51 (2), 1111-1126An extensive series of radical salts formed by the organic donor bis(ethylenedithio)tetrathiafulvalene (ET), the paramagnetic tris(oxalato)ferrate(III) anion [Fe(C2O4)3]3–, and halobenzene guest molecules has been synthesized and characterized. The change ...
Remote Effects of Axial Ligand Substitution in Heterometallic Cr≡Cr···M Chains
Michael Nippe, Yevgeniya Turov, and John F. BerryInorganic Chemistry2011 50 (21), 10592-10599Remote Effects of Axial Ligand Substitution in Heterometallic Cr≡Cr···M Chains
Michael Nippe, Yevgeniya Turov, and John F. BerryInorganic Chemistry2011 50 (21), 10592-10599The heterometallic complexes CrCrM(dpa)4Cl2 (dpa = 2,2′-dipyridylamide) featuring linear Cl–Cr≡Cr···M–Cl chains can regiospecifically be modified via axial ligand substitution to yield OTf–Cr≡Cr···M–Cl chains (OTf = triflate) with M being Fe, Mn, or Co. ...
Full Text HTMLTools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Received: August 03, 2009
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
