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Palladium: It Forms Unique Nano-Sized Carbonyl Clusters

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Evgueni G. Mednikov and Lawrence F. Dahl

Department of Chemistry, University of Wisconsin–Madison, Madison, WI 53706

J. Chem. Educ., 2009, 86 (10), p 1135

DOI: 10.1021/ed086p1135

Publication Date (Web): October 1, 2009

Section:

History, Education, and Documentation

Abstract

In response to the question "What is your favorite element?" the appeal of palladium is described.

Keywords (Audience):

General Public

Keywords (Domain):

Inorganic Chemistry

Keywords (Feature):

National Chemistry Week

Keywords (Subject):

Palladium

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This article has been cited by 2 ACS Journal articles (2 most recent appear below).

Faradaurate Nanomolecules: A Superstable Plasmonic 76.3 kDa Cluster
Amala Dass
Journal of the American Chemical Society2011 133 (48), 19259-19261
- Faradaurate Nanomolecules: A Superstable Plasmonic 76.3 kDa Cluster
  Amala Dass
  Journal of the American Chemical Society2011 133 (48), 19259-19261
  Information on the emergence of the characteristic plasmonic optical properties of nanoscale noble-metal particles has been limited, due in part to the problem of preparing homogeneous material for ensemble measurements. Here, we report the identification,...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
CO-Induced Formation of an Interpenetrating Bicuboctahedral Au₂Pd₁₈ Kernel in Nanosized Au₂Pd₂₈(CO)₂₆(PEt₃)₁₀: Formal Replacement of an Interior (μ₁₂-Pd)₂ Fragment in the Corresponding Known Isostructural Homopalladium Pd₃₀(CO)₂₆(PEt₃)₁₀ with Nonisovalent (μ₁₂-Au)₂ and Resulting Experimental/Theoretical Implications
Evgueni G. Mednikov, Sergei A. Ivanov, and Lawrence F. Dahl
Inorganic Chemistry2011 50 (22), 11795-11806
- CO-Induced Formation of an Interpenetrating Bicuboctahedral Au₂Pd₁₈ Kernel in Nanosized Au₂Pd₂₈(CO)₂₆(PEt₃)₁₀: Formal Replacement of an Interior (μ₁₂-Pd)₂ Fragment in the Corresponding Known Isostructural Homopalladium Pd₃₀(CO)₂₆(PEt₃)₁₀ with Nonisovalent (μ₁₂-Au)₂ and Resulting Experimental/Theoretical Implications
  Evgueni G. Mednikov, Sergei A. Ivanov, and Lawrence F. Dahl
  Inorganic Chemistry2011 50 (22), 11795-11806
  Initially isolated from Pd10(CO)12(PEt3)6 (5) and Au(SMe2)Cl precursors in a two-step carbon monoxide (CO)-involved procedure, the nanosized interpenetrating bicuboctahedral gold (Au)–palladium (Pd) Au2Pd28(CO)26(PEt3)10 (1) was then directly obtained in ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links