An Esterification Kinetics Experiment That Relies on the Sense of Smell

Deborah C. Bromfield-Lee and Maria T. Oliver-Hoyo
Department of Chemistry, North Carolina State University, Raleigh, NC 27695
J. Chem. Educ., 2009, 86 (1), p 82
DOI: 10.1021/ed086p82
Publication Date (Web): January 1, 2009

Abstract

This experiment involves an esterification synthesis to study reaction kinetics where students explore these topics utilizing the sense of smell rather than the traditional approach of using spectroscopic methods. Students study the effects of various factors including the concentration of the carboxylic acid and the amounts of the catalyst or alcohols added. The kinetics in relation to the molecular structure is studied by changing the chain lengths and branching of alcohols or the carboxylic acids and inferring the effects on rates of the reaction from the rates of ester detection. Since many esters have naturally occurring aromas that are pleasant and easily recognized, this experiment studies esterification kinetics using the sense of smell to detect the emergence of the ester aroma formed during the reaction. Feedback from students strongly suggests their interest in the experiment as they discovered that their sense of smell could be used as an analytical tool.

Keywords (Audience):

Second-Year Undergraduate

Keywords (Domain):

Organic Chemistry

Keywords (Pedagogy):

Hands-On Learning / Manipulatives

Keywords (Subject):

Esters

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

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    Learning Organic Chemistry through a Study of Semiochemicals

    Johannes Pernaa and Maija Aksela
    Journal of Chemical Education2011 88 (12), 1644-1647
    • Learning Organic Chemistry through a Study of Semiochemicals

      Johannes Pernaa and Maija Aksela
      Journal of Chemical Education2011 88 (12), 1644-1647

      The topics of nature, for example semiochemicals, are motivating topics, which can be used to teach organic chemistry at high school level. The history, classifications, a few important applications of semiochemicals, and an semiochemical that can be ...

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History

  • Received: August 03, 2009

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