Factors Influencing the Distribution of Lindane and Other Hexachlorocyclohexanes in the Environment

Kathleen Walker*
U.S. EPA, National Center for Environmental Assessment, 401 M Street SW, Mail Code 8601-D, Washington, D.C. 20460
Daniel A. Vallero and Robert G. Lewis
U.S. EPA, National Exposure Research Laboratory, Research Triangle Park, North Carolina 27711
Environ. Sci. Technol., 1999, 33 (24), pp 4373–4378
DOI: 10.1021/es990647n
Publication Date (Web): November 4, 1999
Copyright © 1999 American Chemical Society

Abstract

This review examines the potential for γ-hexachlorocyclohexane (HCH) to be transformed into other isomers of HCH. HCH residues are among the most widely distributed and frequently detected organochlorine contaminants in the environment. The potential environmental and human health risks associated with these residues have prompted Canada, the United States, and Mexico to consider the development of a North American Regional Action Plan (NARAP) to assess and mitigate HCH pollution. More information on the propensity of γ-HCH to transform into other isomers is essential to the development of an effective regional management program. The high relative concentrations of α-HCH in the Arctic suggest that γ-HCH may be transformed into other isomers in the environment. Laboratory studies show that significant photoisomerization of γ-HCH to α-HCH is possible. However, field studies do not find evidence for significant isomerization of γ-HCH, and recent environmental samples suggest that α-HCH residues are declining as the use of technical HCH has ended in most parts of the world. Alternative explanations for the patterns of isomer contamination are discussed.

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History

  • Published In Issue December 15, 1999
  • Received for review June 7, 1999
    Revised manuscript received October 4, 1999
    Accepted October 12, 1999

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