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Organoplatinum(II) and -(IV) and organopalladium(II) and -(IV) complexes of a macrocyclic thioether: x-ray crystal structure of Pt(C6H5)2(9S3), an example of exodentate 1,4,7-trithiacyclononane (9S3)

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Martin A. Bennett, Allan J. Canty, Josef K. Felixberger, Louis M. Rendina, Christopher Sunderland, Anthony C. Willis

Inorg. Chem., 1993, 32 (10), pp 1951–1958

DOI: 10.1021/ic00062a013

Publication Date: May 1993

Note: In lieu of an abstract, this is the article's first page.

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This article has been cited by 8 ACS Journal articles (5 most recent appear below).

Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes
Ansis Maleckis and Melanie S. Sanford
Organometallics2011 30 (24), 6617-6627
- Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes
  Ansis Maleckis and Melanie S. Sanford
  Organometallics2011 30 (24), 6617-6627
  This paper describes the synthesis of a series of PdIV complexes containing modular monoanionic tridentate facially coordinated NNN and NNC donor ligands. In all cases, these complexes are stable to reductive elimination for a minimum of several days in ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Chelating Effect as a Driving Force for the Selective Formation of Heteroligated Pt(II) Complexes with Bidentate Phosphino-Chalcoether Ligands
Mari S. Rosen, Alexander M. Spokoyny, Charles W. Machan, Charlotte Stern, Amy Sarjeant, and Chad A. Mirkin
Inorganic Chemistry2011 50 (4), 1411-1419
- Chelating Effect as a Driving Force for the Selective Formation of Heteroligated Pt(II) Complexes with Bidentate Phosphino-Chalcoether Ligands
  Mari S. Rosen, Alexander M. Spokoyny, Charles W. Machan, Charlotte Stern, Amy Sarjeant, and Chad A. Mirkin
  Inorganic Chemistry2011 50 (4), 1411-1419
  The halide-induced ligand rearrangement reaction (HILR) has been employed to provide selective and exclusive in situ formation of heteroligated Rh(I), Pd(II), and Pt(II) complexes with bidentate phosphino-chalcoether ligands. To gain insights on the ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications
S. Masoud Nabavizadeh, Sepideh Habibzadeh, Mehdi Rashidi, and Richard J. Puddephatt
Organometallics2010 29 (23), 6359-6368
- Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications
  S. Masoud Nabavizadeh, Sepideh Habibzadeh, Mehdi Rashidi, and Richard J. Puddephatt
  Organometallics2010 29 (23), 6359-6368
  The mechanism of oxidative addition of ethyl iodide to [PtMe2(2,2′-bipyridine)], 1, has been investigated by product analysis and by study of secondary deuterium kinetic isotope effects (KIEs), using the reagents C2H5I, C2D5I, CH3CD2I, and CD3CH2I. The ...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
Petr Sehnal, Richard J. K. Taylor and Ian J. S. Fairlamb
Chemical Reviews2010 110 (2), 824-889
- Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis
  Petr Sehnal, Richard J. K. Taylor and Ian J. S. Fairlamb
  Chemical Reviews2010 110 (2), 824-889
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
Intramolecular Metal···Sulfur Interactions of Platinum(II) 1,4,7-Trithiacyclononane Complexes with Bipyridyl Ligands: The Relationship between Molecular and Electronic Structures
Tyler W. Green, Rachel Lieberman, Neal Mitchell, Jeanette A. Krause Bauer, and William B. Connick
Inorganic Chemistry2005 44 (6), 1955-1965
- Intramolecular Metal···Sulfur Interactions of Platinum(II) 1,4,7-Trithiacyclononane Complexes with Bipyridyl Ligands: The Relationship between Molecular and Electronic Structures
  Tyler W. Green, Rachel Lieberman, Neal Mitchell, Jeanette A. Krause Bauer, and William B. Connick
  Inorganic Chemistry2005 44 (6), 1955-1965
  Five platinum(II) 1,4,7-trithiacyclononane (ttcn) complexes with bidentate-substituted 2,2‘-bipyridine ligands have been prepared and structurally characterized: [Pt(bpy)(ttcn)](PF6)2 (bpy = 2,2‘-bipyridine), triclinic, P1̄, a = 10.2529(3) Å, b = 10.7791(...
  Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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Research Article

Organoplatinum(II) and -(IV) and organopalladium(II) and -(IV) complexes of a macrocyclic thioether: x-ray crystal structure of Pt(C6H5)2(9S3), an example of exodentate 1,4,7-trithiacyclononane (9S3)

Citing Articles

Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes

Facial Tridentate Ligands for Stabilizing Palladium(IV) Complexes

Chelating Effect as a Driving Force for the Selective Formation of Heteroligated Pt(II) Complexes with Bidentate Phosphino-Chalcoether Ligands

Chelating Effect as a Driving Force for the Selective Formation of Heteroligated Pt(II) Complexes with Bidentate Phosphino-Chalcoether Ligands

Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications

Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

Emergence of Palladium(IV) Chemistry in Synthesis and Catalysis

Intramolecular Metal···Sulfur Interactions of Platinum(II) 1,4,7-Trithiacyclononane Complexes with Bipyridyl Ligands: The Relationship between Molecular and Electronic Structures