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Coupling of acetylenes held proximate to a metal: alkyne-alkyne interactions in cis-phosphinoacetylene complexes, including structural characterization of the unsymmetrical diphosphine 1-phenyl-2,3-bis(diphenylphoshino)naphthalene and three platinum(II) complexes of Ph2PC.tplbond.CPh
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This article has been cited by 16 ACS Journal articles (5 most recent appear below).
Octahedral Alkynylphosphine Ruthenium(II) Complexes: Synthesis, Structure, and Electrochemistry
Jesús Berenguer, María Bernechea, Julio Fernández, Belén Gil, Elena Lalinde, M. Teresa Moreno, Santiago Ruiz, and Sergio SánchezOrganometallics2011 Article ASAPOctahedral Alkynylphosphine Ruthenium(II) Complexes: Synthesis, Structure, and Electrochemistry
Jesús Berenguer, María Bernechea, Julio Fernández, Belén Gil, Elena Lalinde, M. Teresa Moreno, Santiago Ruiz, and Sergio SánchezOrganometallics2011 Article ASAPReaction of [RuCl2(PPh3)3] with excess of PPh2C≡CFc (Fc = ferrocenyl) proceeds with formation of [trans-RuCl2(PPh2C≡CFc)4] (3), which reacts with HC≡CR (R = Ph, Tol) via dissociative loss of one PPh2C≡CFc ligand to yield vinylidene complexes [mer,cis-RuCl...
Supra–Supra, Supra–Antara, and Stepwise-Diradical Pathways for an Observed 16-Electron Double-[4 + 4] Cycloaddition within Metal-Templated Dialkyne Dimers (PtX2)2(μ-R2PCCCCPR2)2
Aneesh Chacko, Brian T. Sterenberg, and Allan L. L. EastThe Journal of Physical Chemistry A2011 Article ASAPSupra–Supra, Supra–Antara, and Stepwise-Diradical Pathways for an Observed 16-Electron Double-[4 + 4] Cycloaddition within Metal-Templated Dialkyne Dimers (PtX2)2(μ-R2PCCCCPR2)2
Aneesh Chacko, Brian T. Sterenberg, and Allan L. L. EastThe Journal of Physical Chemistry A2011 Article ASAPQuantum chemistry calculations are used to provide insight into the cycloaddition of two dialkyne chains in initially monocyclic organoplatinum dimers of the type (PtX2)2(μ-R2PC4PR2)2, where X = Cl or Me and R = Ph or Me. Previous experimental studies ...
A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne
Jordan A. Tsui and Brian T. SterenbergOrganometallics2009 28 (17), 4906-4908A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne
Jordan A. Tsui and Brian T. SterenbergOrganometallics2009 28 (17), 4906-4908Coordination of bis-phosphino diyne substrates to mixed platinum and tungsten metal templates results in a templated 4 + 2 alkyne−diyne cycloaddition reaction to form an aryne intermediate, which abstracts two H atoms to form an arene ring. The aryne ...
Redox-Active, Multinuclear (Ferrocenylethynyl)phosphanes and Their Palladium and Platinum Complexes
Thomas Baumgartner, Marcel Fiege, Florian Pontzen, and Rocio Arteaga-MüllerOrganometallics2006 25 (23), 5657-5664Redox-Active, Multinuclear (Ferrocenylethynyl)phosphanes and Their Palladium and Platinum Complexes
Thomas Baumgartner, Marcel Fiege, Florian Pontzen, and Rocio Arteaga-MüllerOrganometallics2006 25 (23), 5657-5664A series of new (ferrocenylethynyl)phosphanes and their corresponding Pd and Pt complexes were investigated. Thermal analysis indicated the complexes are potential precursors for nanocomposite magnetic ceramics, and electrochemical investigations revealed ...
Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes
Ana García, Julio Gómez, Elena Lalinde, and M. Teresa MorenoOrganometallics2006 25 (16), 3926-3934Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes
Ana García, Julio Gómez, Elena Lalinde, and M. Teresa MorenoOrganometallics2006 25 (16), 3926-3934The reactivities of several pentafluorophenyl mononuclear platinum(II) complexes bearing different alkynyldiphenylphosphines, under thermal and photochemical conditions, have been examined. In all cases, cyclization reactions have been promoted to afford ...
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- Published In Issue November, 1993
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