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Article

Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains

Marek Samoc*^†, Gulliver T. Dalton^†^‡, John A. Gladysz*^§, Qinglin Zheng^§, Yasen Velkov, Hans Ågren*, Patrick Norman^# and Mark G. Humphrey*^‡^§

Laser Physics Centre, Australian National University, Canberra ACT 0200, Australia, Department of Chemistry, Australian National University, Canberra ACT 0200, Australia, Institut f

r Organische Chemie and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander Universit

t Erlangen-N

rnberg, Henkestrasse 42, 91054 Erlangen, Germany, Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842−3012, Department of Theoretical Chemistry, Royal Institute of Technology, Roslagstullsbacken 15, S-106 91 Stockholm, Sweden, and Department of Physics, Chemistry and Biology, Link

ping University, SE-581 83 Link

ping, Sweden

Inorg. Chem., 2008, 47 (21), pp 9946–9957

DOI: 10.1021/ic801145c

Publication Date (Web): October 1, 2008

* To whom correspondence should be addressed. (M.S.) E-mail: Marek.Samoc@anu.edu.au. Phone: +61 2 6125 4611. Fax: +61 2 6125 0029. (J.A.G.) E-mail: gladysz@mail.chem.tamu.edu or John.Gladysz@chemie.uni-erlangen.de. Phone: +1 979 845 1399. Fax: +1 979 845 4719. (H.A.) E-mail: agren@TheoChem.kth.se. Phone: +46 8 5537 8416. Fax: +46 8 5537 8590. (M.G.H.) E-mail: Mark.Humphrey@anu.edu.au. Phone: +61 2 6125 2927. Fax: +61 2 6125 0760.

†

Laser Physics Centre, Australian National University.

‡

Department of Chemistry, Australian National University.

Friedrich-Alexander Universitt Erlangen-Nrnberg.

Texas A&M University.

Royal Institute of Technology.

Linkping University.

Abstract

The wavelength dependence of the cubic nonlinearity of ligated platinum-terminated polyynes trans,trans-{(p-MeC₆H₄)₃P}₂(p-MeC₆H₄)Pt(CC)_nPt(p-C₆H₄Me){P(p-C₆H₄Me)₃}₂ (n = 3−6, 8, 10, 12) has been examined by femtosecond Z-scan studies in the wavelength range 520−1500 nm and the results rationalized by density functional theory calculations on the model complexes trans,trans-(H₃P)₂(C₆H₅)Pt(CC)_nPt(C₆H₅)(PH₃)₂ (n = 2−8, 10, 12). Although the final states for one- and two-photon transitions are not the same in these centrosymmetric molecules, the Z-scan studies reveal coincidences in one-photon absorption with features in the frequency dependencies of both real and imaginary parts of the cubic hyperpolarizability, as well as inflections in the frequency dependencies of the real part of γ that correspond to resonances in the imaginary part of γ. The theoretical studies suggest that the linear absorption spectra are dominated by X¹A_g → n¹B_3u transitions, with the first state of B_3u symmetry playing a steadily diminishing role upon oligoyne chain lengthening. The theoretical studies also predict a red-shift of two-photon absorption (TPA) profile with increasing conjugation length, and a significant enhancement on proceeding from the shortest to the longest chromophore, trends that are observed experimentally. The experimental low-energy TPA maxima for these complexes can be approximated by a simple Gaussian profile. The sp-carbon chain-length dependence of linear and nonlinear absorption maxima enable an estimate (neglecting saturation) of 660 and 1000 nm for the infinite carbon chain, carbyne.