Acyclic N-Halamine Coated Kevlar Fabric Materials: Preparation and Biocidal Functions

Jie Luo and Yuyu Sun*
Biomedical Engineering Program, University of South Dakota, Sioux Falls, South Dakota 57107
Ind. Eng. Chem. Res., 2008, 47 (15), pp 5291–5297
DOI: 10.1021/ie800021p
Publication Date (Web): June 25, 2008
Copyright © 2008 American Chemical Society
* To whom correspondence should be addressed. Phone: (605) 275-8793. E-mail: yuyu.sun@usd.edu.

Abstract

Polymethacrylamide (PMAA) was coated onto the surfaces of Kevlar fabrics through the in situ polymerization of methacrylamide (MAA) within coating polymer binders. Upon chlorine bleach treatment, the amide groups of the coated PMAA side chains were transformed into stable acyclic N-halamines. The resultant fabric materials provided potent, durable, and rechargeable biocidal activities against E. coli (gram-negative bacteria), S. aureus (gram-positive bacteria), C. tropicalis (fungi), MS2 virus, and Bacillus subtilis spores. The excellent thermal and mechanical properties of the original Kevlar fabrics were successfully retained after the coating treatment.

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History

  • Published In Issue August 06, 2008
  • Article ASAPJune 25, 2008
  • Received: January 4, 2008
    Revised: April 7, 2008
    Accepted: May 5, 2008

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