Tracer studies with radioactive oxygen-15. Exchange between carbon dioxide and water

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This article has been cited by 5 ACS Journal articles (5 most recent appear below).

• 

  H₂CO₃ Forms via HCO₃⁻ in Water

  András Stirling and Imre Pápai
  The Journal of Physical Chemistry B2010 114 (50), 16854-16859

  • H₂CO₃ Forms via HCO₃⁻ in Water

    András Stirling and Imre Pápai
    The Journal of Physical Chemistry B2010 114 (50), 16854-16859

    According to the generally accepted picture of CO2 dissolution in water, the formation of H2CO3 proceeds in a single step that involves the attack of a water oxygen on the CO2 carbon in concert with a proton transfer to a CO2 oxygen. In the present work, ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Kinetics and Mechanism of Peroxymonocarbonate Formation

  Ekaterina V. Bakhmutova-Albert, Huirong Yao, Daniel E. Denevan, and David E. Richardson
  Inorganic Chemistry2010 49 (24), 11287-11296

  • Kinetics and Mechanism of Peroxymonocarbonate Formation

    Ekaterina V. Bakhmutova-Albert, Huirong Yao, Daniel E. Denevan, and David E. Richardson
    Inorganic Chemistry2010 49 (24), 11287-11296

    The kinetics and mechanism of peroxymonocarbonate (HCO4−) formation in the reaction of hydrogen peroxide with bicarbonate have been investigated for the pH 6−9 range. A double pH jump method was used in which 13C-labeled bicarbonate solutions are first ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Determination of Oxygen Sources for Oxidation of Benzene on TiO₂ Photocatalysts in Aqueous Solutions Containing Molecular Oxygen

  Thuan Duc Bui, Akira Kimura, Shigeru Ikeda and Michio Matsumura
  Journal of the American Chemical Society2010 132 (24), 8453-8458

  • Determination of Oxygen Sources for Oxidation of Benzene on TiO₂ Photocatalysts in Aqueous Solutions Containing Molecular Oxygen

    Thuan Duc Bui, Akira Kimura, Shigeru Ikeda and Michio Matsumura
    Journal of the American Chemical Society2010 132 (24), 8453-8458

    Photocatalytic oxidation of benzene to CO2 was studied in aqueous solutions using different kinds of TiO2 powders, and isotopic oxygen tracers (H218O and 18O2) were used to investigate the oxidation process. Phenol was produced as a main intermediate in ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Do Stable Nanobubbles Exist in Mixtures of Organic Solvents and Water?

  Annette Häbich, William Ducker, Dave E. Dunstan and Xuehua Zhang
  The Journal of Physical Chemistry B2010 114 (20), 6962-6967

  • Do Stable Nanobubbles Exist in Mixtures of Organic Solvents and Water?

    Annette Häbich, William Ducker, Dave E. Dunstan and Xuehua Zhang
    The Journal of Physical Chemistry B2010 114 (20), 6962-6967

    Several recent papers have described the existence of stable nanobubbles in bulk, which is surprising given that the high curvature of these bubbles is expected to place such bubbles under a high pressure and therefore lead to rapid dissolution. Here, we ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Comprehensive Study of the Hydration and Dehydration Reactions of Carbon Dioxide in Aqueous Solution

  Xiaoguang Wang, William Conway, Robert Burns, Nichola McCann and Marcel Maeder
  The Journal of Physical Chemistry A2010 114 (4), 1734-1740

  • Comprehensive Study of the Hydration and Dehydration Reactions of Carbon Dioxide in Aqueous Solution

    Xiaoguang Wang, William Conway, Robert Burns, Nichola McCann and Marcel Maeder
    The Journal of Physical Chemistry A2010 114 (4), 1734-1740

    The reversible interactions of dissolved CO2 with H2O and OH− to form H2CO3 and HCO3− in aqueous solution have been investigated using spectrophotometric stopped-flow measurements. The progress of the reactions was monitored via indicators coupled to the ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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