Total synthesis and absolute stereochemical assignment of gilvocarcin M.

Takashi Matsumoto, Takamitsu Hosoya, Keisuke Suzuki

J. Am. Chem. Soc., 1992, 114 (9), pp 3568–3570

DOI: 10.1021/ja00035a069

Publication Date: April 1992

Note: In lieu of an abstract, this is the article's first page.

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Article

Total synthesis and absolute stereochemical assignment of gilvocarcin M.

PDF

Rh-Catalyzed Cyclization of 3-Aryloxycarbonyldiazonaphthoquinones for the Synthesis of β-Phenylnaphthalene Lactones and Formal Synthesis of Pradimicinone

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A Strategy for the Synthesis of Anthraquinone-Based Aryl-C-glycosides

An Inverse Electron Demand Diels–Alder-Based Total Synthesis of Defucogilvocarcin V and Some C-8 Analogues

A Comprehensive History of Arynes in Natural Product Total Synthesis

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Synthesis of Dihydrobenzisoxazoles by the [3 + 2] Cycloaddition of Arynes and Oxaziridines

Combined Directed Remote Metalation−Transition Metal Catalyzed Cross Coupling Strategies: The Total Synthesis of the Aglycones of the Gilvocarcins V, M, and E and Arnottin I

A New Tandem Reaction of Benzyne: One-Pot Synthesis of Aryl Amines Containing Anthracene

Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

Concise Synthesis of Arnottin I and (−)-Arnottin II

Nickel-Catalyzed Synthesis of Benzocoumarins: Application to the Total Synthesis of Arnottin I

Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides: Intramolecular Studies Leading to New Intermolecular Reactions

A Brief and Convergent Synthetic Route to Defucogilvocarcin M Chromophore: The Formal Synthesis of WS-5995 A and C

1,4-Difluoro-2,5-dimethoxybenzene as a Precursor for Iterative Double Benzyne−Furan Diels−Alder Reactions

Biaryl Synthesis via Direct Arylation: Establishment of an Efficient Catalyst for Intramolecular Processes

Concise Three-Component Synthesis of Defucogilvocarcin M

Regioselective Synthesis of Unsymmetrical C-Aryl Glycosides Using Silicon Tethers as Disposable Linkers

On the Verge of Axial Chirality: Atroposelective Synthesis of the AB-Biaryl Fragment of Vancomycin^,

Glycosylation via Cp₂ZrCl₂/AgClO₄-Mediated Activation of Anomeric Sulfoxides

Synthesis of the Benzophenone Fragment of Balanol via an Intramolecular Cyclization Event

General Synthesis Route to Benanomicin-Pradimicin Antibiotics

Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules

Fluoronaphthalene Building Blocks via Arynes: A Solution to the Problem of Positional Selectivity

Model studies towards the synthesis of gilvocarcin M

Palladacycles as Reactive Intermediates

Synthesis of 1-C-(2,5-diphenyl-3,4-diarylphenyl)alditols

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Total synthesis and absolute stereochemical assignment of gilvocarcin M.

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