Hexakis(fluorodimethylsilyl)benzene, Hexakis(methoxydimethylsilyl)benzene, and Related Compounds. Novel Neutral Pentacoordinate Structures for Silicon and Merry-Go-Round Degenerate Fluorine Migration

Keisuke Ebata, Taro Inada, Chizuko Kabuto, Hideki Sakurai

J. Am. Chem. Soc., 1994, 116 (8), pp 3595–3596

DOI: 10.1021/ja00087a054

Publication Date: April 1994

Note: In lieu of an abstract, this is the article's first page.

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Article

Hexakis(fluorodimethylsilyl)benzene, Hexakis(methoxydimethylsilyl)benzene, and Related Compounds. Novel Neutral Pentacoordinate Structures for Silicon and Merry-Go-Round Degenerate Fluorine Migration

PDF

Disilylfluoronium Ions—Synthesis, Structure, and Bonding

Intramolecular Halogen Stabilization of Silylium Ions Directs Gearing Dynamics

“Inverse Sandwich” Complexes of Perhalogenated Cyclohexasilane

Synthesis and Anion Affinity of a Bidendate Sulfonium Fluorosilane Lewis Acid

Dynamics of Si−H−Si Bridges in Agostically Stabilized Silylium Ions

Synthesis and Reactivity of a Tetragallium Macrocycle

Synthesis of B/Si Bidentate Lewis Acids, o-(Fluorosilyl)(dimesitylboryl)benzenes, and Their Fluoride Ion Affinity

Hydrogen- and Fluorine-Bridged Disilyl Cations and Their Use in Catalytic C−F Activation

Stereochemical Flexibility of Bis(amidomethyl)dichlorogermanes. A Novel Dissociative Mechanism of Ligand Exchange in Neutral Hexacoordinated Bischelate Complexes

A Quartz Crystal Microbalance Method for Rapid Detection and Differentiation of Shiga Toxins by Applying a Monoalkyl Globobioside as the Toxin Ligand

Tautomeric Equilibrium between Penta- and Hexacoordinate Silicon Chelates. A Chloride Bridge between Two Pentacoordinate Silicons

Theoretical Study of Activation of Oxirane by Bidentate Acids

Synthesis of Si-containing cyclic ureas

Hypervalent Silicon and Phosphorus Atoms in Single Molecules: Synthesis and Properties of Phosphoranylalkoxysilicates and a Phosphoranyloxysilicate

Molecular Design of Neutral Intramolecular Complexes Bearing Two Silicon Atoms Anchored by a Carbonyl Oxygen Atom:N,N′-Bis(silylmethyl)propylene Ureas

Pentacoordination of boron, carbon, aluminum, and silicon atoms in organic compounds: Anab initio study

X-Ray Crystal Structure and Dynamic Behavior of Pentafluoro-9,10-disila-9,10-dihydroanthracene Anion Salts Having Transannular 1,4-Fluorine Bridge.

Dynamic stereochemistry of hypervalent silicon, germanium and tin compounds containing amidomethyl C, O-chelating ligands

Das Heptafluortrisilacyclohexan-Anion, ein neuartiges fluktuierendes Silicat mit raschem intramolekularem Fluoridaustausch: Synthese und dynamisches Verhalten

Synchronized Fluorine Exchange with Ring Inversion of Pentafluoro-1,4-disilacyclohexane Anion.

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Hexakis(fluorodimethylsilyl)benzene, Hexakis(methoxydimethylsilyl)benzene, and Related Compounds. Novel Neutral Pentacoordinate Structures for Silicon and Merry-Go-Round Degenerate Fluorine Migration

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