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Efficient total synthesis of (.+-.)-anatoxin a
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This article has been cited by 5 ACS Journal articles (5 most recent appear below).
Stereoselective Synthesis of Polypropionate Units and Heterocyclic Compounds by Cyclopropylcarbinol Ring-Opening with Mercury(II) Salts
Christophe Meyer, Nicolas Blanchard, Magali Defosseux, and Janine CossyAccounts of Chemical Research2003 36 (10), 766-772Stereoselective Synthesis of Polypropionate Units and Heterocyclic Compounds by Cyclopropylcarbinol Ring-Opening with Mercury(II) Salts
Christophe Meyer, Nicolas Blanchard, Magali Defosseux, and Janine CossyAccounts of Chemical Research2003 36 (10), 766-772The mercury(II)-mediated electrophilic ring-opening reaction of various cyclopropylcarbinol derivatives bearing adjacent stereocenters and a remote nucleophilic functional group provides a useful strategy for synthesizing compounds bearing several ...
Strategic Use of Pinacol-Terminated Prins Cyclizations in Target-Oriented Total Synthesis
Larry E. Overman and Lewis D. PenningtonThe Journal of Organic Chemistry2003 68 (19), 7143-7157Strategic Use of Pinacol-Terminated Prins Cyclizations in Target-Oriented Total Synthesis
Larry E. Overman and Lewis D. PenningtonThe Journal of Organic Chemistry2003 68 (19), 7143-7157An important objective of contemporary synthesis endeavors is the development of new transformations that rapidly evolve molecular complexity in a stereocontrolled fashion. One approach toward this goal is to combine two or more distinct reactions into a ...
Asymmetric Synthesis of (−)-Anatoxin-a via an Asymmetric Cyclization Using a New Ligand for Pd-Catalyzed Alkylations
Barry M. Trost and Johan D. OslobJournal of the American Chemical Society1999 121 (13), 3057-3064Asymmetric Synthesis of (−)-Anatoxin-a via an Asymmetric Cyclization Using a New Ligand for Pd-Catalyzed Alkylations
Barry M. Trost and Johan D. OslobJournal of the American Chemical Society1999 121 (13), 3057-3064Palladium-catalyzed asymmetric allylic alkylations have been explored in the context of medium-sized ring substrates, intramolecular vs intermolecular processes involving attack on a formally meso -allyl intermediate in the desymmetrization, and the ...
Steric and Electronic Influences on the Diastereoselectivity of the Rh2(OAc)4-Catalyzed C−H Insertion in Chiral Ester Diazoanilides: Synthesis of Chiral, Nonracemic 4-Substituted 2-Pyrrolidinones
Andrew G. H. Wee, Baosheng Liu, and Douglas D. McLeodThe Journal of Organic Chemistry1998 63 (13), 4218-4227Steric and Electronic Influences on the Diastereoselectivity of the Rh2(OAc)4-Catalyzed C−H Insertion in Chiral Ester Diazoanilides: Synthesis of Chiral, Nonracemic 4-Substituted 2-Pyrrolidinones
Andrew G. H. Wee, Baosheng Liu, and Douglas D. McLeodThe Journal of Organic Chemistry1998 63 (13), 4218-4227A series of N-substituted N-(4-methoxyphenyl)--(alkoxycarbonyl)--diazoacetanilides, 10 and ent-10, wherein the alkoxy unit is a chiral auxiliary group [()-7 or (+)-8)], was prepared. The Rh2(OAc)4-catalyzed intramolecular CH insertion reaction of 10 ...
Asymmetric Syntheses, Opioid Receptor Affinities, and Antinociceptive Effects of 8-Amino-5,9-methanobenzocyclooctenes, a New Class of Structural Analogues of the Morphine Alkaloids
Arthur G. Schultz, Aihua Wang, Carlos Alva, Alice Sebastian, Stanley D. Glick, Darlene C. Deecher, and Jean M. BidlackJournal of Medicinal Chemistry1996 39 (10), 1956-1966Asymmetric Syntheses, Opioid Receptor Affinities, and Antinociceptive Effects of 8-Amino-5,9-methanobenzocyclooctenes, a New Class of Structural Analogues of the Morphine Alkaloids
Arthur G. Schultz, Aihua Wang, Carlos Alva, Alice Sebastian, Stanley D. Glick, Darlene C. Deecher, and Jean M. BidlackJournal of Medicinal Chemistry1996 39 (10), 1956-1966Several 8-amino-5,9-methanobenzocyclooctenes have been prepared by asymmetric organic synthesis techniques. Opioid receptor affinity studies have revealed the virtual absence of enantioselectivity for receptor binding, particularly at the -receptor, for ...
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- Published In Issue December, 1985
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