Circumambulatory hexa- and heptamethylbicyclo[3.1.0]hexenyl cations

R. F. Childs, S. Winstein

J. Am. Chem. Soc., 1974, 96 (20), pp 6409–6417

DOI: 10.1021/ja00827a026

Publication Date: October 1974

Note: In lieu of an abstract, this is the article's first page.

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Article

Circumambulatory hexa- and heptamethylbicyclo[3.1.0]hexenyl cations

1,3-Cationic Alkylidene Migration of Nonclassical Carbocation: A Density Functional Theory Study on Gold(I)-Catalyzed Cycloisomerization of 1,5-Enynes Containing Cyclopropene Moiety

Generation and Reaction of a Phenyl-Substituted Cyclopentadienyl Cation Annelated with Two Homoadamantene Frameworks

Theoretical Study of the Heptamethylbenzenium Ion. Intramolecular Isomerizations and C₂, C₃, C₄ Alkene Elimination

Decamethylsilicocene Chemistry: Unprecedented Multistep Reactions of a Silicon(II) Compound with the Heterocumulenes CO₂, COS, CS₂, and RNCS (R = Methyl, Phenyl)

Structure of protonated 1,3,4,5-tetramethylbicyclo[3.1.0]hex-3-en-2-one hexachloroantimonate

Quantum mechanical prediction of hydride locations in transition-metal systems

Photoisomerizations of protonated phenols. Extension of the photochemistry of cyclohexa-2,5-dienones

Pendular rearrangement of epimeric 3b,4,4a,5-tetramethyl-3b,4,4a,5-tetrahydro-4H-cyclopropa[a]phenalen-5-yl cations

Energy barriers to carousel rearrangements of carbocations: Quantum-chemical calculations vs. experiment

Bis(pentamethylcyclopentadienyl)methanol: Synthese, Struktur und Derivatisierung

Stufenweiser Abbau des Benzvalens in der Ligandensphäre eines Übergangsmetalls

Umlagerungen freier Radikale, VII. Elektrocyclische und sigmatrope Umlagerungen des Bicyclo[3.1.0]hexenyl-Radikals

Umlagerungen freier Radikale, VIII.endo/exo-Isomerisierung 6-substituierter Bicyclo[3.1.0] hexenyl-Radikale

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