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AN INSTANCE OF TRIVALENT CARBON: TRIPHENYLMETHYL.
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This article has been cited by 51 ACS Journal articles (5 most recent appear below).
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Wenshan Ren, Guofu Zi, and Marc D. WalterOrganometallics2012 31 (2), 672-679The reduction of [η5-1,2,4-(Me3C)3C5H2]2ThCl2 (1) with potassium graphite in the presence of 2,2′-bipyridine gives the purple thorium bipy metallocene [η5-1,2,4-(Me3C)3C5H2]2Th(bipy) (2) in good yield. Complex 2 has been characterized by various ...
Asymmetric Diels–Alder and Ficini Reactions with Alkylidene β-Ketoesters Catalyzed by Chiral Ruthenium PNNP Complexes: Mechanistic Insight
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Christoph Schotes, Martin Althaus, Raphael Aardoom, and Antonio MezzettiJournal of the American Chemical Society2012 134 (2), 1331-1343Hydride abstraction from the β-position of the enolato ligand of the previously reported complex [Ru(3a–H)(PNNP)]PF6 (5a; 3a–H is the enolate of 2-tert-butoxycarbonylcyclopentanone) with (Ph3C)PF6 gives the dicationic complex [Ru(6a)(PNNP)]2+ (7a) as a ...
Harnessing Redox-Active Ligands for Low-Barrier Radical Addition at Oxorhenium Complexes
Cameron A. Lippert, Kenneth I. Hardcastle, and Jake D. SoperInorganic Chemistry2011 50 (20), 9864-9878Harnessing Redox-Active Ligands for Low-Barrier Radical Addition at Oxorhenium Complexes
Cameron A. Lippert, Kenneth I. Hardcastle, and Jake D. SoperInorganic Chemistry2011 50 (20), 9864-9878The addition of an [X]+ electrophile to the five-coordinate oxorhenium(V) anion [ReV(O)(apPh)2]− {[apPh]2– = 2,4-di-tert-butyl-6-(phenylamido)phenolate} gives new products containing Re–X bonds. The Re–X bond-forming reaction is analogous to oxo transfer ...
Unprecedented Radical−Radical Reaction of a [2.2]Paracyclophane Derivative Containing an Imidazolyl Radical Moiety
Sayaka Hatano, Ken Sakai, and Jiro AbeOrganic Letters2010 12 (18), 4152-4155Unprecedented Radical−Radical Reaction of a [2.2]Paracyclophane Derivative Containing an Imidazolyl Radical Moiety
Sayaka Hatano, Ken Sakai, and Jiro AbeOrganic Letters2010 12 (18), 4152-4155Pseudogem-DPIM-DPI[2.2]PC dimer (3), with a C−N bond between the [2.2]paracyclophane ([2.2]PC) moiety and the imidazole ring, was synthesized. This is the first crystallographic observation of a highly sterically constrained 1-ene-2,5-cyclohexadiene ...
Structurally Dynamic Conjugated Polymers
Andrew G. Tennyson, Brent Norris and Christopher W. BielawskiMacromolecules2010 43 (17), 6923-6935Structurally Dynamic Conjugated Polymers
Andrew G. Tennyson, Brent Norris and Christopher W. BielawskiMacromolecules2010 43 (17), 6923-6935Conjugated polymers (CPs) have become essential to a diverse array of fields, ranging from biosensing to photovoltaics to optoelectronic materials. Given their widespread use, there is a growing need for variants whose functions may be modulated via ...
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- Published In Issue November, 1900
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