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The Enantioselective Tsuji Allylation

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Douglas C. Behenna and Brian M. Stoltz*

Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125

J. Am. Chem. Soc., 2004, 126 (46), pp 15044–15045

DOI: 10.1021/ja044812x

Publication Date (Web): October 28, 2004

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, stoltz@caltech.edu

Abstract

The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry.

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Published In Issue November 24, 2004
Received August 27, 2004

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Communication

The Enantioselective Tsuji Allylation

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

Total Synthesis of (−)-Acutumine

Enantiospecific Total Syntheses of Kapakahines B and F

Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

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