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Highly Efficient Addition of Activated Methylene Compounds to Alkenes Catalyzed by Gold and Silver

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Xiaoquan Yao and Chao-Jun Li*

Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada

J. Am. Chem. Soc., 2004, 126 (22), pp 6884–6885

DOI: 10.1021/ja0482637

Publication Date (Web): May 15, 2004

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, cj.li@mcgill.ca

Abstract

A highly efficient intermolecular addition of 1,3-diketones to alkenes catalyzed by AuCl₃/AgOTf was developed. A mechanistic rationale for the reaction has been proposed via a α-C−H activation.

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Published In Issue June 09, 2004
Received March 26, 2004

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Communication

Highly Efficient Addition of Activated Methylene Compounds to Alkenes Catalyzed by Gold and Silver

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes

A Highly Efficient Three-Component Coupling of Aldehyde, Alkyne, and Amines via C−H Activation Catalyzed by Gold in Water

Gold(I)-Catalyzed Intermolecular Addition of Phenols and Carboxylic Acids to Olefins

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