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Ketone Deprotonation Mediated by Mono- and Heterobimetallic Alkali and Alkaline Earth Metal Amide Bases: Structural Characterization of Potassium, Calcium, and Mixed Potassium−Calcium Enolates

Supporting Info

Xuyang He,^† Bruce C. Noll,^† Alicia Beatty,^† Robert E. Mulvey,*^‡ and Kenneth W. Henderson*^†;

Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, and Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, Scotland G1 1XL, UK

J. Am. Chem. Soc., 2004, 126 (24), pp 7444–7445

DOI: 10.1021/ja048750m

Publication Date (Web): May 26, 2004

†

University of Notre Dame.

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

‡

University of Strathclyde.

, r.e.mulvey@strath.ac.uk, ; , khenders@nd.edu

Abstract

Potassium, calcium, and mixed potassium−calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

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