Communication
Cobalt-Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides
In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.
Abstract

Conversion of olefins to azides was achieved with high Markovnikov selectivity for a broad range of alkenes using 6 mol % Co(BF4)·6H2O and ligand 1, with 3 equiv of TsN3 as nitrogen source and simple silanes (PhSiH3, TMDSO).
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History
- Published In Issue June 15, 2005
- Received April 5, 2005
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