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Communication

Palladium(II)-Catalyzed Intramolecular Diamination of Unfunctionalized Alkenes

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Jan Streuff, Claas H. Hövelmann, Martin Nieger, and Kilian Muñiz*

Kekul-Institut fr Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany

J. Am. Chem. Soc., 2005, 127 (42), pp 14586–14587

DOI: 10.1021/ja055190y

Publication Date (Web): October 4, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, kilian.muniz@uni-bonn.de

Abstract

Intramolecular diamination reactions are described which yield cyclic ureas as direct products of an oxidative alkene transformation in the presence of palladium acetate and iodosobenzene diacetate as terminal oxidant. The reaction is truly catalytic in metal catalyst and represents the proof of principle for this elusive type of alkene oxidation.

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Published In Issue October 26, 2005
Received July 31, 2005

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Communication

Palladium(II)-Catalyzed Intramolecular Diamination of Unfunctionalized Alkenes