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Communication

Intermolecular Ene Reactions Utilizing Oxazolones and Enol Ethers

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Jason S. Fisk and Jetze J. Tepe*

Department of Chemistry, Michigan State University, East Lansing, Michigan 48823

J. Am. Chem. Soc., 2007, 129 (11), pp 3058–3059

DOI: 10.1021/ja0627904

Publication Date (Web): February 28, 2007

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, tepe@cem.msu.edu

Abstract

We report herein an intermolecular ene reaction using oxazolones with enol ethers which results in the formation of novel quaternary amino esters in near quantitative yields. The overall reaction transformation closely resembles an intermolecular version of the Conia-ene reaction. The reactions are uncatalyzed and occur under very mild conditions.

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Published In Issue March 21, 2007
Received April 21, 2006

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Communication

Intermolecular Ene Reactions Utilizing Oxazolones and Enol Ethers

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Synthesis of tert-Alkyl Amino Hydroxy Carboxylic Esters via an Intermolecular Ene-Type Reaction of Oxazolones and Enol Ethers

Au(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions of Münchnones with Electron-Deficient Alkenes

Chiral Anion-Mediated Asymmetric Ring Opening of meso-Aziridinium and Episulfonium Ions

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