Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction

Takahiko Akiyama,* Hisashi Morita, and Kohei Fuchibe
Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, 171-8588 Tokyo, Japan
J. Am. Chem. Soc., 2006, 128 (40), pp 13070–13071
DOI: 10.1021/ja064676r
Publication Date (Web): September 20, 2006
Copyright © 2006 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, takahiko.akiyama@gakushuin.ac.jp

Abstract

Abstract Image

Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give tetrahydroquinoline derivatives with excellent enantioselectivity.

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History

  • Published In Issue October 11, 2006
  • Received July 12, 2006

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